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It is often assumed that a small proportion of a given vehicle fleet produces a disproportionate amount of air pollution emissions. If true, policy actions to target the highly polluting section of the fleet could lead to significant improvements in air quality. In this paper, high-emitter vehicle subsets are defined and their contributions to the total fleet emission are assessed. A new approach, using enrichment factor in cumulative Pareto analysis is proposed for detecting high emitter vehicle subsets within the vehicle fleet. A large dataset (over 94,000 remote-sensing measurements) from five UK-based EDAR (emission detecting and reporting system) field campaigns for the years 2016-17 is used as the test data. In addition to discussions about the high emitter screening criteria, the data analysis procedure and future issues of implementation are discussed. The results show different high emitter trends dependent on the pollutant investigated, and the vehicle type investigated. For example, the analysis indicates that 23 % and 51 % of petrol and diesel cars were responsible for 80 % of NO emissions within that subset of the fleet, respectively. Overall, the contributions of vehicles that account for 80 % of total fleet emissions usually reduce with EURO class improvement, with the subset fleet emissions becoming more homogenous. The high emitter constituent was more noticeable for pollutant PM compared with the other gaseous pollutants, and it was also more prominent for petrol cars when compared to diesel ones.
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http://dx.doi.org/10.1016/j.scitotenv.2022.159814 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Novosibirsk 630090, Russia.
While fluorene-containing materials are widely used in organic optoelectronics as bright emitters and hole semiconductors, their diazafluorene analogues have been poorly explored, though their nitrogen atoms could result in electron transport and bring sensory abilities. Here, we report the synthesis, characterization, and detailed study of a series of 4,5-diazafluorene-derivatives with different donor/acceptor substituents and organic semiconductors based on these molecules. The crystal structures of all the materials were solved by X-ray diffraction, indicating the presence of extensive π-stacking and anisotropic charge-transfer pathways.
View Article and Find Full Text PDFCarbohydr Polym
November 2025
Department of Food Science and Agricultural Chemistry, McGill University, Quebec H9X 3V9, Canada.
Passive daytime radiative cooling (PDRC) offers a sustainable solution to global energy challenges by dissipating heat without energy input. However, conventional PDRC materials face trade-offs between biodegradability, color integration, optical transparency, and mechanical robustness. Herein, a biomimetic, structurally colored PDRC film fabricated via evaporation-induced self-assembly of cellulose nanocrystals (CNCs), betaine, and polyvinyl alcohol was developed.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
State Key Laboratory of Advanced Materials for Intelligent Sensing and Key Laboratory of Organic Integrated Circuits, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Institute of Molecular Plus, Department of Chemistry, Tianjin University, Tianjin 300072, China.
Incorporating boron atoms into organic macrocycles imparts unique chemical, electronic, and optical properties. The concept of making use of dative boron-nitrogen (B ← N) bonds for the construction of macrocycles has been proposed, but very few examples have been prepared with functional structures, much less pillar-like and other prismatic macrocycles, and their various functionalities have not been fully exploited. Here, we introduce a "functional molecular wall" synthetic protocol based on the self-assembly characteristics of B ← N dative bonds to construct highly symmetrical macrocycles, forming a quasi-pentagonal-shaped macrocycle (named [5]pyBN-) with a pillar-like structure.
View Article and Find Full Text PDFAppl Radiat Isot
August 2025
Radioisotope Centre POLATOM, National Centre for Nuclear Research, Andrzeja Sołatana 7, 05-400 Otwock, Poland.
Terbium-161 (T = 6.89 d) is a low-energy β emitter (β 460 and 522 keV). It also emits γ radiation (25.
View Article and Find Full Text PDFChem Sci
August 2025
Department of Chemistry and Chemical Biology, Rutgers University Piscataway NJ 08854 USA
Near-infrared (NIR) luminescent materials are pivotal for advanced optoelectronic and biomedical applications, yet attaining efficient emission in the NIR-II region (950-1400 nm) remains challenging. Here, we introduce a ligand cationization strategy for designing copper(i) iodide-organic hybrid materials that emit in the NIR-II region (920-1120 nm) with PLQYs up to 8.58%.
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