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Article Abstract
The cycloaddition reaction of carbon dioxide (CO) is a highly economic solution to becoming carbon-neutral. Herein, we have designed and synthesized a robust zinc(II)-organic framework (Zn-Ade-TCPE) by a function-directed strategy. Zn-Ade-TCPE possesses uncommon hexagonal cages with Lewis acid-base bifunctional sites and displays a high adsorption capacity for CO. At room temperature and atmospheric pressure, Zn-Ade-TCPE exhibits outstanding activity, selectivity, and recyclability in the cycloaddition reaction of epoxides with CO because of the synergistic effect of multiple active sites and confined cavities.
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| http://dx.doi.org/10.1021/acs.inorgchem.2c03144 | DOI Listing |
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