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Atmospheric mercury (Hg) is largely assimilated by vegetation and subsequently transferred to the soil by litterfall, which highlights the role of forests as one of the largest global Hg sinks within terrestrial ecosystems. We assessed the pool of Hg in the aboveground biomass (leaves, wood, bark, branches and twigs), the Hg deposition flux through litterfall over two years (by sorting fallen biomass in leaves, twigs, reproductive structures and miscellaneous) and its accumulation in the soil profile in a deciduous forest dominated by Betula alba from SW Europe. The total Hg pool in the aboveground birch biomass was in the range 532-683 mg ha, showing the following distribution by plant tissues: well-developed leaves (171 mg ha) > twigs (160 mg ha) > bark (159 mg ha) > bole wood (145 mg ha) > fine branches (25 mg ha) > thick branches (24 mg ha) > newly sprouted leaves (20 mg ha). The total Hg deposition fluxes through litterfall were 15.4 and 11.7 μg m yr for the two years studied, with the greatest contribution coming from birch leaves (73 %). In the soil profile, the pool of Hg in the mineral soil (37.0 mg m) was an order of magnitude higher than in the organic horizons (1.0 mg m), mostly conditioned by parameters such as soil bulk density and thickness, total C and N contents and the presence of certain Al compounds.
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http://dx.doi.org/10.1016/j.scitotenv.2022.158937 | DOI Listing |
Chem Sci
September 2025
Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University 99 Shangda Road Shanghai 200444 China
Lithium metal is deemed to be the ultimate anode material for high-energy-density and fast-charging lithium batteries. However, issues of dendritic deposition and frangible solid electrolyte interphases must be resolved for lithium metal anodes. Herein, a hybrid interfacial layer, hierarchical hollow nanospheres assembled from lithiophilic imine-based covalent organic frameworks and built-in Ag sites (Ag@ICOFs), has been applied to regulate the interfacial lithium ion flux and enhance the anode stability for effectively inhibiting dendrite formation.
View Article and Find Full Text PDFEcotoxicol Environ Saf
September 2025
Center for Global Health, the Key Laboratory of Modern Toxicology, Ministry of Education, Department of Hygienic Analysis and Detection, School of Public Health, School of Public Health, Nanjing Medical University, Nanjing 211166, China. Electronic address:
Bisphenol F (BPF), a widely used substitute for bisphenol A (BPA), has raised growing concerns due to its potential metabolic toxicity. Recent studies suggest that BPF exposure is associated with lipid accumulation and non-alcoholic fatty liver disease (NAFLD)-like changes, however, the underlying mechanisms remain poorly understood. This study was performed to investigate the BPF-induced NAFLD-like changes through the lipid degradative pathway, which via an unrecognized defect of lipophagy mediated by Adipose Triglyceride Lipase (ATGL)-Sirtuin 1 (SIRT1)-Peroxisome proliferator-activated receptor α (PPARα) signaling axis.
View Article and Find Full Text PDFJ Hazard Mater
August 2025
School of Chemistry and Chemical Engineering, Hainan University, Haikou 570228, PR China. Electronic address:
In this study, a multifunctional composite membrane (PDMS@CNT@COF@CF) integrating superhydrophobic, efficient photo-thermal conversion, and electrical insulation properties was developed through a functional co-design strategy. The material was constructed by depositing a covalent organic framework (COF) on the surface of carbon nanotube (CNT) via room temperature in situ polymerization. It was then robustly anchored onto a cotton fabric (CF) substrate through polydimethylsiloxane (PDMS) coating.
View Article and Find Full Text PDFInvest Ophthalmol Vis Sci
September 2025
Eye Institute and Department of Ophthalmology, Eye and ENT Hospital, Fudan University, Shanghai, China.
Purpose: To develop and characterize a novel mouse model of granular corneal dystrophy type II (GCD2) using CRISPR/Cas9 technology and explore the underlying pathogenesis of transforming growth factor-beta-induced protein (TGFBIp) aggregation.
Methods: CRISPR/Cas9 technology was employed to introduce the R124H mutation in the TGFBI gene of mice. Genomic sequencing and polymerase chain reaction confirmed the mutation.
Sci Total Environ
September 2025
The Robert H. Smith Faculty of Agriculture, Food and Environment, Department of Soil and Water Sciences, The Hebrew University of Jerusalem, Rehovot, Israel. Electronic address:
Tropospheric ozone (O) is a major air pollutant that negatively affects human health and vegetation, and plays a central role in climate change and atmospheric chemistry. Current simulations of tropospheric O concentrations in climate and air-quality models are significantly limited by the inaccurate representation of O dry deposition rate-particularly in urban areas, where field measurements remain scarce. We hypothesize that O dry deposition in the urban environment is controlled by factors similar to those over vegetation, albeit via potentially different mechanisms.
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