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Fluids containing colloidal suspensions of nanometer-sized particles (nanofluids) have been extensively investigated in recent decades with promising results. Driven by the increase in the thermal conductivity of these new thermofluids, this topic has been growing in order to improve the thermal capacity of a series of applications in the thermal area. However, when it comes to measure nanofluids (NFs) thermal conductivity, experimental results need to be carefully analyzed. Hence, in this review work, the main traditional and new techniques used to measure thermal conductivity of the NFs are presented and analyzed. Moreover, the fundamental parameters that affect the measurements of the NFs' thermal conductivity, such as, temperature, concentration, preparation of NFs, characteristics and thermophysical properties of nanoparticles, are also discussed. In this review, the experimental methods are compared with the theoretical methods and, also, a comparison between experimental methods are made. Finally, it is expected that this review will provide a guidance to researchers interested in implementing and developing the most appropriate experimental protocol, with the aim of increasing the level of reliability of the equipment used to measure the NFs thermal conductivity.
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http://dx.doi.org/10.3390/nano12152526 | DOI Listing |
Phys Chem Chem Phys
September 2025
Department of Physics, Indian Institute of Technology Jodhpur, N.H. 62, Nagaur Road, Karwar, Jodhpur, Rajasthan, 342030, India.
We report an anomalous temperature-induced transition in thermal conductivity in the germanene monolayer around a critical temperature = 350 K. Equilibrium molecular dynamics simulations reveal a transition from ∼ scaling below the to ∼ above, contrasting with conventional ∼ behavior. This anomalous scaling correlates with the long-scale characteristic timescale obtained from double exponential fitting of the heat current autocorrelation function.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China.
Developing solid electrolytes with high ionic conductivity, a high voltage window, low flammability, and excellent interface compatibilities with both the anode and cathode for lithium-metal batteries is still a great challenge but highly desirable. Herein, we achieve this target through an in situ copolymerization of vinyl ethylene carbonate (VEC) together with acrylonitrile (AN) under fitting ratios inside a porous polyacrylonitrile (PAN) fiber membrane doped with flame-retardant decabromodiphenyl ethane (DBDPE) molecules. The received fiber-reinforced polycarbonate-based composite electrolyte with an ultrathin thickness of 13 μm exhibits good internal interfacial compatibility because of the same AN structure and superior flame-retardant performance due to the doped DBDPE molecules.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Jiangsu Provincial Key Lab for The Chemistry and Utilization of Agro-forest Biomass, Jiangsu Key Lab of Biomass Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China.
Aramid films are potential separator candidates for high-safety lithium-ion batteries (LIBs) due to their inherent flame retardancy and outstanding thermal stability. However, both weak liquid electrolyte wettability and poor mechanical properties of aramid separators for lithium-ion batteries result in low ionic conductivity and unsatisfactory electrochemical performance for LIBs. Herein, a novel asymmetric porous composite separator composed of a relatively dense nanocellulose (CNC) layer and a porous poly(m-phenylene isophthalamide) (PMIA) supporting layer has been fabricated by using a water-induced phase conversion process.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin, 150040, China. Electronic address:
With the exhaustion of fossil fuels, prior phase change materials are characterized by such drawbacks as poor thermal conductivity, weak shape stability, and high costs. Therefore, the preparation of phase change materials with brilliant thermal-insulating properties, high thermal conductivity, and leakage-free properties has emerged as a crucial research focus. Herein, a sericultural mulberry branch-derived (SMB) composite phase change material was prepared by deep eutectic solvent pretreated SMB and vacuum-assisted impregnated paraffin wax with cupric oxide (CuO).
View Article and Find Full Text PDFAdv Mater
September 2025
Graduate School of Carbon Neutrality, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Ulsan, 44919, Republic of Korea.
Spiro-OMeTAD has remained the benchmark hole-transporting material (HTM) in state-of-the-art perovskite solar cells, owing to its favorable energy level alignment and excellent interfacial compatibility. However, its practical implementation is critically hindered by the intrinsic instabilities introduced by conventional dopants such as lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and 4-tert-butylpyridine (tBP). While these dopants enhance electrical conductivity, they concurrently initiate multiple degradation pathways-including ionic migration, radical deactivation, and moisture/thermal-induced morphological failure-thereby compromising device longevity and reproducibility.
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