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Of profound astrobiological interest, Enceladus appears to have a global saline subsurface ocean, indicating water-rock reaction at present or in the past, an important mechanism in the moon's potential habitability. Here, we investigate how salinity and the partition of heat production between the silicate core and the ice shell affect ocean dynamics and the associated heat transport-a key factor determining equilibrium ice shell geometry. Assuming steady-state conditions, we show that the meridional overturning circulation of the ocean, driven by heat and salt exchange with the poleward-thinning ice shell, has opposing signs at very low and very high salinities. Regardless of these differing circulations, heat and fresh water converge toward the equator, where the ice is thick, acting to homogenize thickness variations. Among scenarios explored here, the pronounced ice thickness variations observed on Enceladus are most consistent with heating that is predominantly in the ice shell and a salinity of intermediate range.
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http://dx.doi.org/10.1126/sciadv.abm4665 | DOI Listing |
Small
August 2025
College of Chemical Engineering, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China.
N-doped porous carbon materials are promising potassium-ion battery anodes for overcoming the depressing rate performance and poor cycling stability issues associated with the oversized radius of K-ion. However, the relatively low initial coulombic efficiency (ICE) as a result of porous structure and doped heteroatoms may limit the future application of potassium-ion batteries. Herein, a novel N-doped porous graphite-like carbon armored with dense amorphous shell is synthesized through a Trojan horse strategy by etching and doping the carbon matrix from inside out using oxidized coal tar pitch coated CN as precursor.
View Article and Find Full Text PDFBiomacromolecules
September 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Chemical Engineering, Nanjing Forestry University, Longpan Road 159, Nanjing 210037, China.
Chitin/protein nanofibrils are extracted from decalcified crab shells using 100 mM hydrochloric acid and ultrasonication or high-pressure homogenization, achieving a 94% recovery rate. Further increases in the temperature or duration enhance hydrolysis, leading to a significant reduction in the nanofibril size. The increase in the number of acidic amino acids within the nanofibrils enhances electrostatic repulsion, promoting their dispersion under acidic conditions.
View Article and Find Full Text PDFMicrosc Microanal
July 2025
Department of Microstructure Physics and Alloy Design, Max-Planck Institute for Sustainable Materials (Formerly Eisenforschung), Max-Planck-Strasse 1, Düsseldorf 40237, Germany.
The folding and structure of biomacromolecules depend on the three-dimensional distributions of their constituents, and this ultimately controls their functionalities and interactions with other biomacromolecules. Atom probe tomography (APT) with its unparalleled compositional sensitivity at nanoscale spatial resolution, could provide complementary information to cryo-electron microscopy, yet routine APT analysis of biomacromolecules in their native state remains challenging. Here, we used a solution containing ferritin as a model biomacromolecule, and following plunge freezing in liquid nitrogen (LN2), performed cryogenic specimen preparation via lift-out, and APT analysis.
View Article and Find Full Text PDFBioresour Technol
December 2025
College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410000, China. Electronic address:
Camellia oleifera shell (COS), a lignin- and hemicellulose-rich cultivation byproduct, offers significant potential for resource extraction. In this study, we developed an integrated biorefinery approach using mild metal chloride-catalyzed hydrothermal pretreatment to vaporize COS waste. Under optimized conditions (0.
View Article and Find Full Text PDFCommun Chem
August 2025
School of Physics and Astronomy, University of Leeds, Leeds, UK.
In 2034, NASA Dragonfly will arrive at Titan's Selk crater to study an environment where molten ice has potentially interacted with organics. Some models suggest that Titan has a sub-surface ocean enriched in ammonia, a molecule that forms a deep eutectic with water, implying that it strongly perturbs water's intermolecular structure. In anticipation of the Dragonfly mission, and to understand the effects of the addition of ammonia to liquid water, we used neutrons to probe the structure of a 20.
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