Preparation and characterization of low-cost nano-particle material using for brilliant green removal.

A low-cost nano-particle material was successfully prepared using waste . Batch adsorption experiments were carried out to investigate the effect of different operating conditions on the removal of brilliant green (BG) dye from an aqueous solution. SEM images of nano-particles (PPNP) declared roughness of the surfaces and TEM images indicated a spheroid shape with an average particle size of 37 nm. The specific surface area of the PPNP was 354.46 m/g and the particle size had a mean diameter of 613.4 nm. The active nano-particle suspension showed a net negative charge (-29 mV) at natural pH. The XRD pattern of PPNP displayed an average crystallite size of 13.50 nm and EDS analysis shows that the PPNP consists of 83% carbon. The experimental work showed that the removal of BG had optimum removal efficiency at 20 min, 0.3 g adsorbent mass, 25 °C, and pH 8. The kinetic data can be described well with the pseudo-second-order model and the isotherm data was found to fit the Dubinin model. The thermodynamic study proved that BG adsorption on PPNP was physisorption (Δ = -5.949 kJ/mol) and spontaneous at low temperature (Δ = -17.193 kJ/mol, Δ = -0.0382 kJ/mol. k)This study used an agriculture waste (pomegranate peels) to prepare an environmentally friendly and low-cost adsorbent within the nano-scale by thermal activation. The nano-particles prepared were shown to be a promising adsorbent, demonstrating high surface area and well-developed porosity. The prepared adsorbent will have a great impact on wastewater treatment technology and possible applications at a large scale.