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A critical review of the articles dealing with biochar in terms of the reuse of biomass waste in building materials and its impact on material properties was conducted using five different electronic databases; thirteen articles were selected for this critical review. Biochar was used as a replacement for cement and aggregate in cementitious composites and as an addition in wood polypropylene composites and plasters. The biochar dosages ranged from 0.5% to 40%; in most composites, the addition of biochar increased strength and reduced thermal conductivity and the bulk density of fresh mortars. Also, biochar dosages of 0.5-2% decreased, while dosages of 10-40% increased water absorption and penetration on cementitious composites. The selected studies mainly introduced biochar use in building materials as a means of biomass waste reduction and its reuse for various purposes, while carbon footprint reduction was addressed in only a few of them. Biochar-containing building material's capability of capturing CO from the air was also observed (0.033 mmol CO g to 0.138 mmol CO g). The results also showed that mortars with CO-unsaturated biochar had better mechanical and physical properties than mortars with CO-saturated biochar. Selected studies showed biochar-containing building materials have a great potential for carbon footprint reduction. However, there is a lack of comprehensive studies about biochar use in building materials concerning climate change mitigation.
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http://dx.doi.org/10.1016/j.jenvman.2022.114704 | DOI Listing |
J Am Chem Soc
September 2025
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States.
Understanding how molecular aggregation influences nonlinear optical properties is essential for advancing organic fluorophores in imaging, sensing, and photonic applications. However, the relationship between the molecular aggregation and the magnitude of nonlinear two-photon absorption cross-section remains underexplored. Here, we systematically investigate the aggregation-dependent two-photon absorption properties of the fluorophore TPAPhCN by tuning the degree of aggregation.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
School of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, 341000, China; School of Resources and Civil Engineering, GanNan University of Science and Technology, Ganzhou, 341000, China.
Herein, organic/inorganic multiple adsorption sites were constructed on halloysite to intensify the selective adsorption performance of the adsorbent for Al(III) in rare earth solutions. The adsorption heat behavior and thermodynamics of the composite for different ion systems were investigated using microcalorimetry. The results showed that chitosan formed a mesoporous membrane on the acid-treated calcined halloysite (HalH) substrate through a strong electron interaction between the nitrogen atom of the amino group and the oxygen atom of SiO structure on HalH.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China. Electronic address:
Transition metal fluorides because of the high electronegativity of fluorine may enhance the local electron density of the metal sites and promote water molecule dissociation and charge transfer. However, enhancing the intrinsic activity of fluorides to improve material stability remains a challenge. Herein, we develop an innovative four-step synthetic strategy (electrochemical deposition → co-precipitation → ligand exchange → in situ fluorination) to engineer three-dimensional porous Fe-doped CoF nanocubes vertically anchored on MXene (Fe-CoF/MXene/NF).
View Article and Find Full Text PDFLangmuir
September 2025
State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing 100041, China.
This article is based on the research background of an early performance of shotcrete under low-temperature environments. Silica fume (SF) (silicon powder) and nano-CSH are used to improve the effect of the low-temperature environment on the performance of alkali-free (AF) liquid accelerators and early strength of shotcrete. The results show that the 10% SF and 3% nano-CSH composite admixture significantly enhances AF accelerators' performance at 5 °C, reducing initial and final setting times to 3.
View Article and Find Full Text PDFLangmuir
September 2025
Federal University of São Paulo, Laboratory of Hybrid Materials, Diadema, São Paulo 09913-030, Brazil.
This study demonstrates the successful fabrication of nanostructured Langmuir-Blodgett (LB) films combining the conjugated copolymer poly(9,9-dioctylfluorene--3,4-ethylenedioxythiophene) (PDOF--PEDOT) with spherical and triangular silver nanoparticles (AgNP). The LB technique allowed precise control over the molecular arrangement and distribution of the nanoparticles at the air-water interface, resulting in compact, reproducible and structurally ordered nanocomposite films. The structural and morphological properties of the interfacial monolayers and LB films were investigated using surface pressure-area isotherms, Brewster angle microscopy, polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS) and quartz crystal microbalance.
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