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Ultra-thin microwave absorbers have been urgently demanded for electromagnetic applications in recent years. Herein, porous carbon with a "flower cluster" microstructure was synthesized from biomass waste (mango seeds) by a facile activation and carbonization method. The novel structure reduced the density and also improved the impedance matching, dipole polarization, and provided many carbon matrix-air interfaces for interfacial polarization, resulting in superior microwave absorption performance. At an ultra-thin thickness of 1.5 mm, extraordinary microwave absorption was achieved, with a reflection loss (RL) of -42 dB. The effective absorption bandwidth reached 4.2 GHz. The RL can be further improved to -68.4 dB by adjusting the amount of activator to manipulate the structure of porous carbon. In addition, from the simulated radar scattering results, the maximum reduction in the radar cross-section (RCS) reached 30.4 dBm, which can greatly reduce the probability of equipment being detected by radar. This work provides a low-cost and high-performance microwave absorber for electromagnetic stealth technologies.
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http://dx.doi.org/10.1016/j.jcis.2021.12.162 | DOI Listing |
Chem Commun (Camb)
September 2025
University of Belgrade-Faculty of Physical Chemistry, Studentski trg 12-16, Belgrade, Rebublic of Serbia.
Carbon aerogels and xerogels, with their 3D porous architectures, ultralow density, high surface area, and excellent conductivity, have emerged as multifunctional materials for energy and environmental applications. This review highlights recent advances in the synthesis of these materials polymerisation, drying, and carbonisation, as well as the role of novel precursors such as graphene, carbon nanotubes, and biomass. Emphasis is also placed on doped and metal-decorated carbon gels as efficient electrocatalysts for oxygen reduction reactions, enabling four- and two-electron pathways for energy conversion and the production of green HO, respectively.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
College of New Energy and Materials, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, Changping, 102249, China.. Electronic address:
Hard carbon has emerged as the most widely studied and commercialized anode material for sodium-ion batteries (SIBs). However, improving the charge transfer kinetics within the plateau potential range of the hard carbon anode is crucial for the development of fast-charging SIBs. In this study, we prepared a novel composite material, ZAPA-1300, by uniformly mixing starch, asphalt, and zinc oxide (ZnO), followed by a two-step treatment process.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, PR China; Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), Qingdao 266580, PR China. Electronic address:
With the trend of heavy and inferior crude oil, the design of hydrodesulfurization (HDS) catalysts with excellent activity and high active metal utilization is an inevitable trend for the upgrading of refining technology. In this study, a highly dispersed Mo catalyst confined within nitrogen-doped porous carbon (xMo@NC) was prepared using an in situ encapsulation-pyrolysis approach and used in the HDS reaction of dibenzothiophene (DBT). The methods of XRD, HRTEM, HAADF-STEM, N physisorption, FT-IR, Raman, and XPS were used to carry out thorough microstructural characterization.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Department of Chemistry, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, and iChEM, Fudan University, Shanghai 200438, China. Electronic address:
We present a coordination-inspired strategy for assembling binary nanocrystal superlattices (BNSLs) using CdSe nanotetrapods as symmetry-encoding building blocks. Exploiting their intrinsic tetrahedral geometry, which mimics the sp hybridization of carbon atoms in a diamond lattice, we encode spatially defined binding sites that guide regioselective coassembly with spherical nanocrystals. By tuning the size ratio between components, we achieve both three-dimensional and two-dimensional BNSLs with long-range structural order.
View Article and Find Full Text PDFSmall
September 2025
School of Energy and Chemical Engineering, UNIST, Ulsan, 44919, South Korea.
All-solid-state batteries (ASSBs), equipped with highly ion-conductive sulfide solid electrolytes and utilizing lithium plating/stripping as anode electrochemistry, suffer from 1) chemical vulnerability of the electrolytes with lithium and 2) physical growth of lithium to penetrate the electrolytes. By employing an ordered mesoporous graphitic carbon (OMGC) framework between a sulfide electrolyte layer and a copper current collector in ASSB, the concerns by are addressed 1) minimizing the chemically vulnerable interface (CVI) between electric conductor and solid electrolyte, and 2) allowing lithium ingrowth toward the porous structure via Coble creep, a diffusional deformation mechanism of lithium metal along the lithium-carbon interface. The void volume of the framework is fully filled with lithium metal, despite ionic pathways not being provided separately, even without additional lithiophiles, when an enough amount of lithium is allowed to be plated.
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