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The development of highly active and stable photocatalysts, an effective way to remediate environment pollution and alleviate energy shortages, remains a challenging issue. In this work, a CdInS/In(OH) nanocomposite was deposited in-situ on NiCr-LDH nanosheets by a simple hydrothermal method, and the obtained CdInS/In(OH)/NiCr-LDH heterostructure photocatalysts with multiple intimate-contact interfaces exhibited better photocatalytic activity. The photocatalytic H evolution rate of CdInS/In(OH)/NiCr-LDH increased to 10.9 and 58.7 times that of the counterparts CdInS and NiCr-LDH, respectively. Moreover, the photocatalytic removal efficiency of Cr(VI) increased from 6% for NiCr-LDH and 75% for CdInS to 97% for CdInS/In(OH)/NiCr-LDH. The enhanced photocatalytic performance was attributed to the formation of multi-interfaces with strong interfacial interactions and staggered band alignments, which offered multiple pathways for carrier migration, thus promoting the separation efficiency of photo-excited electrons and holes. This study demonstrates a facile method to fabricate inexpensive and efficient heterostructure photocatalysts for solving environmental problems.
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http://dx.doi.org/10.3390/nano11113122 | DOI Listing |
J Colloid Interface Sci
September 2025
Department of Thermal Science and Energy Engineering, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026, PR China. Electronic address:
Heterojunctions have garnered significant attention in the field of photocatalysis due to their exceptional ability to facilitate the separation of photogenerated charge carriers and their high efficiency in hydrogen reaction. However, their overall photocatalytic performance is often constrained by electron transport rates and suboptimal hydrogen adsorption/desorption kinetics. To address these challenges, this study develops a g-CN/MoS@MoC dual-effect synergistic solid-state Z-type heterojunction, synthesized through the in-situ sulfurization of MoC combined with ultrasonic self-assembly technique.
View Article and Find Full Text PDFInorg Chem
September 2025
Yunnan Key Laboratory of Crystalline Porous Organic Functional Materials, College of Chemical and Materials Engineering, Qujing Normal University, Qujing 655011, China.
Sequential assembly of donor-acceptor components at the molecular level within a MOF is an effective strategy to achieve efficient electron-hole separation for enhancing the activity of photocatalysts. Meanwhile, the highly efficient and selective functionalization of tetrahydroisoquinoline (THIQ) under mild conditions remains an urgent demand in both the scientific and industrial communities. This work reports a donor-acceptor MOF photocatalyst () constructed by the coordinated assembly of donor and acceptor components, in which a naphthalene unit serves as an electron donor and a perylenediimide unit as an electron acceptor.
View Article and Find Full Text PDFInorg Chem
September 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.
Photocatalysis has emerged as a promising strategy to address water pollution caused by heavy metals and antibiotics. Zeolites exhibit significant potential in petrochemical catalysis; however, the development of zeolite-based photocatalysts remains a critical challenge for researchers. Herein, a novel Z-scheme heterojunction was designed and fabricated on the titanium-silicon zeolite TS-1 by modifying g-CN via a simple calcination process.
View Article and Find Full Text PDFInt J Phytoremediation
September 2025
Innovative Food Technologies Development Application and Research Center, Gölköy Campus Bolu, Bioenvironment and Green Synthesis Research Group, Bolu Abant İzzet Baysal University, Bolu, Türkiye.
This study presents an eco-friendly approach for the green synthesis of manganese oxide nanoparticles (MnONPs) using () (einkorn wheat) seed extract as a reducing and stabilizing agent. The synthesized MnONPs were characterized by UV-Vis, XRD, FTIR, SEM-EDX, BET, and zeta potential analyses, which confirmed their crystalline nature, spherical morphology, and mesoporous structure with a surface area of 41.50 m/g.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
College of Smart Materials and Future Energy, Fudan University, Songhu Road 2005, Shanghai, 200438, P.R. China.
Solar-driven photocatalytic oxygen reduction reaction using covalent organic frameworks (COFs) offers a promising approach for sustainable hydrogen peroxide (HO) production. Despite their advantages, the reported COFs-based photocatalysts suffer insufficient photocatalytic HO efficiency due to the mismatched electron-proton dynamics. Herein, we report three one-dimensional (1D) COF photocatalysts for efficient HO production via the hydrogen radical (H•) mediated concerted electron-proton transfer (CEPT) process.
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