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Complex electronic phases in strongly correlated electron systems are manifested by broken symmetries in the low-energy electronic states. Some mysterious phases, however, exhibit intriguing energy gap opening without an apparent signature of symmetry breaking (e.g., high- cuprates and heavy fermion superconductors). Here, we report an unconventional gap opening in a heterostructured, iron-based superconductor SrVOFeAs across a phase transition at ∼150 K. Using angle-resolved photoemission spectroscopy, we identify that a fully isotropic gap opens selectively on one of the Fermi surfaces with finite warping along the interlayer direction. This band selectivity is incompatible with conventional gap opening mechanisms associated with symmetry breaking. These findings, together with the unusual field-dependent magnetoresistance, suggest that the Kondo-type proximity coupling of itinerant Fe electrons to localized V spin plays a role in stabilizing the exotic phase, which may serve as a distinct precursor state for unconventional superconductivity.
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http://dx.doi.org/10.1073/pnas.2105190118 | DOI Listing |
Adv Mater
September 2025
School of Materials Science and Engineering, Anhui University, Hefei, 230601, China.
Modulating the electronic structure of catalysts to maximize their power holds the key to address the challenges faced by zinc-iodine batteries (ZIBs), including the shuttle effect and slow redox kinetics at the iodine cathode. Herein, oxygen vacancies is innovatively introduced into CoO lattice to create high-spin-state Co active sites in nonstoichiometric CoO nanocrystals supported by carbon nanofibers (H-CoO/CNFs). This simple strategy intensifies crystal field splitting of Co 3d orbitals, optimizing the spin-orbital coupling between Co 3d orbitals and iodine species.
View Article and Find Full Text PDFRev Sci Instrum
September 2025
Leiden Institute of Physics, Leiden University, 2333CC Leiden, The Netherlands.
Whether at the molecular or cellular scale in organisms, cell-cell adhesion adapts to external mechanical cues arising from the static environment of cells and from dynamic interactions between neighboring cells. Cell-cell adhesion needs to resist detachment forces to secure the integrity and internal organization of organisms. In the past, various techniques have been developed to characterize adhesion properties of molecules and cells in vitro and to understand how cells sense and probe their environment.
View Article and Find Full Text PDFAdv Sci (Weinh)
September 2025
Department of Biomedical Engineering, University of Virginia, Charlottesville, VA, 22908, USA.
Focused Ultrasound (FUS) is the concentration of acoustic energy into a small region to produce therapeutic bioeffects. FUS-induced blood-brain barrier opening (BBBO), a strategy to deliver drugs and genes to the brain, also enhances glymphatic drainage, the brain-specific waste clearance system. Thus, FUS BBBO is a promising strategy for addressing the accumulation of neurotoxic solutes that are characteristic of many neurodegenerative diseases.
View Article and Find Full Text PDFNano Lett
September 2025
Department of Physics and Astronomy and California NanoSystems Institute, University of California, Los Angeles, California 90095, United States.
Moiré superlattices introduce new length and energy scales, enabling discoveries, such as unconventional superconductivity, in 2D systems. This concept has recently been extended to bulk materials with multiple- spin textures, opening exciting opportunities for spin moiré physics. A notable example is EuAgSb, where a spin moiré superlattice (SMS), manifested as a double- spin modulation, induces a superzone gap opening.
View Article and Find Full Text PDFRSC Adv
August 2025
Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU) Riyadh 13318 Saudi Arabia.
Ternary chalcogenides have attracted much interest because of their potential for use in sustainable energy applications due to their tunable electronic, optical, and transport characteristics. This work examined the structural, electronic, optoelectronic, and thermoelectric properties of novel BiPbSe and BiPbTe chalcogenides through density functional theory. The predicted energy gap values measured with the TB-mBJ and PBE-GGA are 1.
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