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This paper presents a new modification of the nanostructure of CaSO·2HO crystals containing nanopores. This nanoporous structure was achieved in phosphogypsum samples that were modified by sodium carbonate and alum. The effects of sodium carbonate and alum on the properties of phosphogypsum were studied. X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods were used to explore the micro-mechanism of the composite system. Subsequently, molecular dynamics simulations were used to study the nanopore structures of the modified CaSO·2HO. The results show that the addition of sodium carbonate and alum reduced the absolute dry density by 23.1% compared with the original phosphogypsum sample, with a bending strength of 2.1 MPa and compressive strength of 7.5 MPa. In addition, new hydration products, sodium sulfate and sodium aluminum sulfate, were formed in the sample doped with sodium carbonate and alum. A new nanostructure of CaSO·2HO crystal containing nanopores was formed. Molecular simulations show that the hydration products were responsible for the surface nanopore formation, which was the main factor leading to an increase in mechanical strength. The presented nanopore structure yields lightweight and high strength properties in the modified phosphogypsum.
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http://dx.doi.org/10.3390/ma14195830 | DOI Listing |
Nanoscale
August 2025
Guizhou Aerospace Linquan Motor Co., Ltd, Guiyang 550081, China.
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View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2025
Federal University of Minas Gerais: Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil.
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November 2025
Institute of Food and Processing, Liaoning Academy of Agricultural Sciences, Shenyang 110161, China.
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September 2025
School of Agriculture and Food Science, University College Dublin, Belfield, Dublin 4, Ireland. Electronic address:
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View Article and Find Full Text PDFJ Hazard Mater
September 2025
Particle Engineering Centre, Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim 7491, Norway. Electronic address:
Spent lithium-ion batteries (LIBs) are a valuable secondary source of lithium, but conventional recovery methods using sodium carbonate (NaCO) often result in sodium contamination, limiting the purity of recovered lithium carbonate (LiCO). The present study introduces a novel process for lithium recovery from industrial black mass (BM) using a CO blend, which addresses the issue of sodium contamination. Lithium was selectively extracted from an industrial black mass through water leaching.
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