Highly efficient removal of DEET by UV-LED irradiation in the presence of iron-containing coagulant.

N,N-Diethyl-3-methyl benzoyl amide (DEET) has been detected as an emerging pollutant in various water bodies because of its widespread use as an insect repellent. In this study, the combination of UV-LED and iron-containing coagulant (FeCl) was used for the elimination of DEET in water. It was found that UV-LED/FeCl (98 %) system presented a favorable removal of DEET compared with UV/FeCl (59 %) and UV-LED/Fe(SO) (81 %) processes at initial pH 3.5. DEET degradation by both UV-LED/FeCl and UV-LED/Fe(SO) processes followed pseudo-first-order kinetics with the calculated pseudo-first-order rate constants (k) of 0.0105 and 0.0046 cm mJ, respectively. The results of ESR analysis and radicals quenching experiments indicated that hydroxyl radicals (OH) and superoxide radicals (O) were responsible for DEET degradation in UV-LED/FeCl process, and the former played the major role. An increase in FeCl dosage was beneficial to the degradation. In the UV-LED/FeCl process, DEET degradation increased with a decrease in pH from 3.5 to 3.0, whereas it was almost completely suppressed with an increase in pH from 4.3 to 6.3. DEET degradation was almost unchanged after the introduction of NO, and it impeded after the addition of humic acid (HA), HCO, and SO. The plausible degradation pathway mainly involved hydroxylation, cleavage of the C-N bond, acetylation, and dealkylation. Among the disinfection by-products (DBPs) evaluated, UV-LED/FeCl pretreatment generally increased the generation of trichloromethane, chloral hydrate, dichloroacetic acid, and trichloroacetic acid, which implied that further assessment of environmental risk was needed during its practical applications.