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The complex tumbling motion of spinning nonspherical objects is a topic of enduring interest, both in popular culture and in advanced scientific research. Here, we report all-optical control of the spin, precession, and nutation of vaterite microparticles levitated by counterpropagating circularly polarized laser beams guided in chiral hollow-core fiber. The circularly polarized light causes the anisotropic particles to spin about the fiber axis, while, regulated by minimization of free energy, dipole forces tend to align the extraordinary optical axis of positive uniaxial particles into the plane of rotating electric field. The end result is that, accompanied by oscillatory nutation, the optical axis reaches a stable tilt angle with respect to the plane of the electric field. The results reveal new possibilities for manipulating optical alignment through rotational degrees of freedom, with applications in the control of micromotors and microgyroscopes, laser alignment of polyatomic molecules, and study of rotational cell mechanics.
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http://dx.doi.org/10.1126/sciadv.abf6053 | DOI Listing |
Int J Biol Macromol
June 2025
School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China. Electronic address:
This work constructed chitosan-based core-shell catalytic nanoreactor (CS/NI/SA@Cu(II)) by free radical polymerization of biomass chitosan and temperature sensitive materials. The CS/NI/SA@Cu(II) were characterized by FT-IR, TG, XPS, SEM, TEM, and EDS to prove the formation of the nanoreactor, and the Cu content was obtained by ICP analysis. The TEM indicated that CS/NI/SA-2 presented a hollow core-shell structure with a size of about 100 nm, and the contact angle of CS/NI/SA-2 was 67°.
View Article and Find Full Text PDFACS Photonics
February 2025
Max Planck Institute for the Science of Light, Staudtstraße 2, 91058 Erlangen, Germany.
We show that twisted single-ring hollow-core fibers can exhibit strong helical dichroism, i.e., a different transmission depending on the orbital angular momentum of the launched light.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
College of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China.
- exhibited significant aggregation-induced Emission (AIE) characteristics, including high brightness (αAIE ≈ 40), robust light stability, a substantial Stokes shift (128 nm), and a high signal-to-noise ratio, effectively overcoming aggregation-caused quenching (ACQ). Derived from the axially chiral -H-BINOL, - was synthesized via nucleophilic cyclization and exhibited pronounced self-assembly properties. Through robust intra- and intermolecular hydrogen bonding interactions, - formed diverse supramolecular structures, including spherical flower-like aggregates, hollow-core triangular tubules, hexagonal tubules, and irregular white block-like stacks.
View Article and Find Full Text PDFInt J Mol Sci
October 2024
Jiangxi Province Key Laboratory of Organic Functional Molecules, Institute of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China.
In this paper, two aggregation-induced emission (AIE) chiral fluorescent materials, S-1 and S-2, were synthesized. The two materials are based on BINOL and H-BINOL backbones, respectively, and large electron-absorbing groups are attached to the chiral backbones through the Knoevenagel reaction. At the same time, the CD signals of these two chiral fluorescent materials are gradually weakened (f gradually increases) as they continue to aggregate.
View Article and Find Full Text PDFACS Nano
June 2024
Nanostructured and Organic Optical and Electronic Materials (NANOrOPT), Department of Physics, University of Antwerp, B-2610 Antwerp, Belgium.