Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
We theoretically investigate high-pressure effects on the atomic dynamics of metallic glasses. The theory predicts compression-induced rejuvenation and the resulting strain hardening that have been recently observed in metallic glasses. Structural relaxation under pressure is mainly governed by local cage dynamics. The external pressure restricts the dynamical constraints and slows down the atomic mobility. In addition, the compression induces a rejuvenated metastable state (local minimum) at a higher energy in the free-energy landscape. Thus, compressed metallic glasses can rejuvenate and the corresponding relaxation is reversible. This behavior leads to strain hardening in mechanical deformation experiments. Theoretical predictions agree well with experiments.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1103/PhysRevLett.126.025502 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
"Silatranization": Surface modification with silatrane coupling agents.
Adv Colloid Interface Sci
August 2025
Cracow University of Technology, Faculty of Chemical Engineering and Technology, Department of Biotechnology and Physical Chemistry, Warszawska 24, 31-155 Cracow, Poland; Photo4Chem, Lea 114, 30-133 Cracow, Poland; Photo HiTech Ltd., Bobrzyskiego 14, 30-348 Cracow, Poland. Electronic address: joanna
Silatranization, a specialized variant of silanization using silatrane compounds, is emerging as a powerful strategy to functionalize material surfaces. Compared to conventional silane coupling agents, silatranes exhibit remarkable hydrolytic stability and enhanced resistance to self-condensation, enabling controllable, water-independent formation of a polysiloxane self-assembled monolayer. This review critically examines the unique structure of silatranyl cages, emphasizing how the intramolecular N->Si bond and chelate effect modulate the silicon center's reactivity toward hydroxyl-decorated surfaces.
View Article and Find Full Text PDFMetal-Organic Crystallized Glasses: Microstructure Formation and Their Properties.
J Am Chem Soc
September 2025
Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.
Partial crystallization within a glass matrix to form microcrystalline domains offers a pathway to glass-ceramic materials with properties distinct from those of both the parent glass and crystalline phases. This concept has been limited to inorganic glasses. Here, we introduce metal-organic crystallized glasses (MOCGs), prepared by controlling the crystallization process within metal-organic framework (MOF) glasses, and explore their properties.
View Article and Find Full Text PDFTuning Magnetism Through Stoichiometric Potassium Intercalation into VOCl.
J Am Chem Soc
September 2025
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Layered van der Waals (vdW) materials, characterized by their interlayer vdW gaps, offer exceptional tunability of magnetic properties via intercalation chemistry. A wide range of magnetic behaviors have been observed in nonmagnetic transition-metal dichalcogenides intercalated with magnetic atoms. Beyond the incorporation of magnetic ions, we propose the controlled alkali-ion intercalation of intrinsic vdW magnets as a strategy to probe and manipulate spin populations and exchange interactions within individual magnetic layers.
View Article and Find Full Text PDFSyntheses, Single-Crystal Structures, and Structural Chemistry of Hexafluoridouranates(V), UF ( = Li-Cs, Ag, Tl, HO), and the Dodecafluoridodiuranate(V) Ba[UF]·1.36HF.
Inorg Chem
September 2025
Arbeitsgruppe Fluorchemie, Anorganische Chemie, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032 Marburg, Germany.
We present the syntheses of the hexafluoridouranates(V) UF ( = Li-Cs, Ag, Tl, HO) and of the dodecafluoridodiuranate(V) Ba[UF]·1.36HF. With the exception of AgUF and HOUF, all compounds were synthesized by reacting the respective metal fluorides with β-UF in anhydrous hydrogen fluoride (aHF).
View Article and Find Full Text PDFThe Formation of Supramolecular Rigid Glass Based on Transparent Deep Eutectic.
Adv Mater
September 2025
College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.
The development of transparent materials with mechanical rigidity and hardness via the non-covalent bonding of low-molecular-weight building blocks is a major challenge. Although various strategies have been developed to improve the mechanical performance of supramolecular materials, they are frequently accompanied by complex designs and tedious syntheses. Therefore, it is urgent to develop perspectives that are fundamentally distinguished from previous strategies.
View Article and Find Full Text PDF