Zinner syndrome is a rare congenital urinary condition, secondary to disruptions in the embryonic development process between the fourth and 13th week of pregnancy, particularly due to abnormalities in the development of the distal mesonephric duct. It is characterized by the triad of unilateral renal agenesis, ipsilateral seminal vesicle cyst, and ipsilateral vas deferens obstruction. We present a case of a young male patient who came to the hospital for a health check-up.
View Article and Find Full Text PDFBeilstein J Nanotechnol
November 2024
This work presents a simple chemical vapour deposition (CVD) method to grow ZnO nanostructures. By annealing Zn powder under atmospheric pressure conditions, we collected nanocrystals with various morphologies, including rods, pencils, sheets, combs, tetrapods, and multilegs. Raman scattering study reveals that the samples are monophasic with a hexagonal structure, and fall into the 6 space group.
View Article and Find Full Text PDFDespite being an excellent surface enhanced Raman scattering (SERS) active material, gold nanoparticles were difficult to be loaded onto the surface of filter paper to fabricate flexible SERS substrates. In this study, electrochemically synthesized gold nanoparticles (e-AuNPs) were deposited on graphene oxide (GO) nanosheets in solution by ultrasonication, resulting in the formation of a GO/Au hybrid material. Thanks to the support of GO, the hybrid material could adhere onto the surface of filter paper, which was immersed into a GO/Au solution for 24 h and dried naturally at room temperature.
View Article and Find Full Text PDFRSC Adv
November 2023
A functional ternary substrate was developed for surface-enhanced Raman scattering (SERS) sensing systems. MnO nanosheets were synthesized by a simple and controllable hydrothermal method, followed by the integration of graphene oxide (GO) nanosheets. Subsequently, MnO/GO nanostructures were decorated with plasmonic Ag nanoparticles (e-AgNPs).
View Article and Find Full Text PDFAnal Methods
October 2023
Crystal violet (CV) is an organic dye that is stabilized by the extensive resonance delocalization of electrons over three electron-donating amine groups. This prevents the molecule from being linked to a metal surface, and therefore, reduces the sensitivity of surface-enhanced Raman scattering (SERS) sensors for this toxic dye. In this work, we improved the sensing performance of a silver-based SERS sensor for CV detection by modifying the active substrate.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2023
Taking advantage of metal-semiconductor junctions, functional nanocomposites have been designed and developed as active substrates for surface-enhanced Raman scattering (SERS) sensing systems. In this work, we prepared three types of nanocomposites based on manganese oxide (MnO) nanostructures and electrochemically synthesized silver nanoparticles (e-AgNPs), which differed according to the morphologies of MnO. The SERS performance of MnO nanosheet/e-Ag (MnO-s/e-Ag), MnO nanorod/e-Ag (MnO-r/e-Ag), and MnO nanowire/e-Ag (MnO-w/e-Ag) was then evaluated using tricyclazole (TCZ), a commonly used pesticide, as an analyte.
View Article and Find Full Text PDFAnal Chim Acta
August 2023
Owing to the effective combination between MoS sheets with CuInS nanoparticles (NPs), a direct Z-scheme heterojunction was successfully constructed and proved as a promising structure to modify the working electrode surface with the aim of enhancing overall sensing performance towards CAP detection. Herein, MoS was employed as a high mobility carrier transport channel with a strong photo-response, large specific surface area, and high in-plane electron mobility, while CuInS acted as an efficient light absorber. This not only offered a stable nanocomposite structure but also created impressive synergistic effects of high electron conductivity, large surface area, highlight exposure interface, as well as favorable electron transfer process.
View Article and Find Full Text PDFA reconfigurable metamaterial absorber (MA) in the microwave region is numerically and experimentally demonstrated based on a multi-layered metamaterial. The proposed structure can be mechanically switched between two different configurations to obtain designated absorption behaviors. By rotating the upper ring layer by multiples of 90 deg, two separated absorption modes of the MA are created.
View Article and Find Full Text PDFThis publisher's note corrects errors in Appl. Opt.61, 9078 (2022)APOPAI0003-693510.
View Article and Find Full Text PDFReconfigurable metasurfaces (RMSs) that enable the switching function of absorption and polarization conversion have attracted increasing attention. However, the design of RMSs to achieve wideband and high efficiency for both absorption and polarization conversion functions simultaneously remains a great challenge. Here, we propose the design of a RMS structure with a high-efficiency cross-polarization conversion and nearly perfect absorption.
View Article and Find Full Text PDFMaterials (Basel)
September 2022
In this paper, we present a flexible magnetic metamaterial structure for enhancing the efficiency of wireless power transfer (WPT) systems operating at 13.56 MHz. The metasurface between transmitter (Tx) and receiver (Rx) coils of the WPT system is constructed of a 3 × 5 metamaterial unit cell array with a total size of 150 × 300 mm.
View Article and Find Full Text PDFDespite the utilization of external magnetic field (MF) in promoting the intrinsic unique features of magnetic nanomaterials in many different applications has been reported, however the origin of MF-dependent electrochemical behaviors as well as the electrochemical response of analytes at the electrode in sensor applications is still not clear. In this report, the influence of MF on the electrolyte's physicochemical properties (polarization, mass transport, charge/electron transfer) and electrode's properties (conductivity, morphology, surface area, interaction, adsorption capability, electrocatalytic ability) was thoroughly investigated. Herein, the working electrode surface was modified with carbon spheres (CSs), magnetic nanoparticles (FeONPs), and their nanocomposites (FeO@CSs), respectively.
View Article and Find Full Text PDFIn this work, Ag@ZnO and Ag@ZnO/MgAC photocatalysts were synthesized using a simple two-step electrochemical method by the addition of magnesium aminoclay (MgAC) as a great stabilizer and a Lewis base, which could donate electrons for reduction of Ag and Zn ions, facilitating uniform formation as well as effective inhibition of aggregation of Ag@ZnO nanoparticles (NPs) on the MgAC matrix. Ag@ZnO and Ag@ZnO/MgAC were investigated for photocatalytic degradation of MB and their antibacterial efficiencies. Ag@ZnO/MgAC showed excellent photocatalytic MB degradation with a performance of 98.
View Article and Find Full Text PDFWe investigated the coupling phenomenon between plasmonic resonance and waveguide modes through theoretical and experimental parametric analyses on the bimetallic waveguide-coupled long-range surface plasmon resonance (Bi-WCLRSPR) structure. The calculation results indicated that the multi-plasmonic coupling gives rise to the enhanced depth-to-width ratio of the reflection dip compared to that of LRSPR excited using a single set of Ag and Teflon. The optimized thickness of Ag(40 nm)/Teflon(700 nm)/Ag(5 nm)/Au(5 nm) was obtained and generated the highest plasmon intensity enhancement, which was 2.
View Article and Find Full Text PDFWe propose a theoretical model to elucidate intermolecular electrostatic interactions between a virus and a substrate. Our model treats the virus as a homogeneous particle having surface charge and the polymer fiber of the respirator as a charged plane. Electric potentials surrounding the virus and fiber are influenced by the surface charge distribution of the virus.
View Article and Find Full Text PDFMoS-GO composites were fabricated by an ultrasonication method at room temperature. Raman spectra, emission scanning electron microscopy (SEM), and transmission electron microscopy (TEM) images were used to study the structural characteristics, morphologies, and sizes of the synthesized materials. An MoS-GO/SPE (screen-printed electrode) was prepared by a facile dropping method and acted as an effective electrochemical sensor toward clenbuterol (CLB) and 4-nitrophenol (4-NP) detection.
View Article and Find Full Text PDFIn this article, we investigated the efficiency of a magnetic resonant wireless power transfer (MR-WPT) in conducting medium and found out an optimal frequency for designing the system. In conducting environment, the eddy current loss is generated by the high-frequency alternating currents in the coils. It is manifested by increased radiation resistance of resonator coil leads to decrease the quality factor (Q-factor), which reduces the wireless power transfer (WPT) efficiency in conducting medium.
View Article and Find Full Text PDFPhys Rev Lett
January 2021
We theoretically investigate high-pressure effects on the atomic dynamics of metallic glasses. The theory predicts compression-induced rejuvenation and the resulting strain hardening that have been recently observed in metallic glasses. Structural relaxation under pressure is mainly governed by local cage dynamics.
View Article and Find Full Text PDFA simple design of a broadband multifunctional polarization converter using an anisotropic metasurface for X-band application is proposed. The proposed polarization converter consists of a periodic array of the two-corner-cut square patch resonators based on the FR-4 substrate that achieves both cross-polarization and linear-to-circular polarization conversions. The simulated results show that the polarization converter displays the linear cross-polarization conversion in the frequency range from 8 to 12 GHz with the polarization conversion efficiency above 90%.
View Article and Find Full Text PDFThe picosecond dynamics of excited charge carriers in the silicon substrate of THz metamaterial antennas was studied at different wavelengths. Time-resolved THz pump-THz probe spectroscopy was performed with light from a tunable free electron laser in the 9.3-16.
View Article and Find Full Text PDFWe theoretically investigate equilibrium behaviors and photothermal effects of a flexible plasmonic metamaterial composed of aramid nanofibers and gold nanoparticles. The fiber matrix is considered as an external field to reconfigure a nanoparticle assembly. We find that the heating process tunes particle-particle and fiber-particle interactions, which alter adsorption of nanoparticles on fiber surfaces or clustering in pore spaces.
View Article and Find Full Text PDFThe photothermal energy conversion in hanging and floating polyaniline (PANi)-cotton fabrics is investigated using a model based on the heat diffusion equation. Perfect absorption and anti-reflection of wet hanging PANi-cotton fabrics cause quick transfer of total incident light into water confining nearly 100% of the sunlight. As a result, a hanging membrane is found to have more attractive properties than a floating above water fabric.
View Article and Find Full Text PDFWe present a numerical study of thermo-tunable broadband-negative-permeability metamaterial based on second-order hybridization operating at the THz regime. The conventional metal is replaced by InSb, in which the temperature-dependent conductivity plays a key role in tuning the separation of second-order-hybridization magnetic-resonance modes. It is demonstrated that the hybridization in a simple disk-pair dimer can be tuned by temperature, leading to a significant broadening of the negative-permeability at THz frequencies.
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