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Article Abstract
The unit cell of the title compound, [Zn(CHNO)]·CHO·CHO, contains two complex mol-ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth-oxy-'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazide} coordinate to the Zn ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by π-π inter-actions between the planar ligand moieties, which are further connected by C⋯O and C⋯C inter-actions. The inter-molecular inter-actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H⋯H (44.8%), H⋯C/C⋯H (22.2%), H⋯O/O⋯H (18.7%) and C⋯C (3.9%) inter-actions.
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| http://dx.doi.org/10.1107/S2056989020000857 | DOI Listing |
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