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We have derived values of the Ultraviolet Index (UVI) at solar noon using the Tropospheric Ultraviolet Model (TUV) driven by ozone, temperature and aerosol fields from climate simulations of the first phase of the Chemistry-Climate Model Initiative (CCMI-1). Since clouds remain one of the largest uncertainties in climate projections, we simulated only the clear-sky UVI. We compared the modelled UVI climatologies against present-day climatological values of UVI derived from both satellite data (the OMI-Aura OMUVBd product) and ground-based measurements (from the NDACC network). Depending on the region, relative differences between the UVI obtained from CCMI/TUV calculations and the ground-based measurements ranged between -5.9% and 10.6%. We then calculated the UVI evolution throughout the 21st century for the four Representative Concentration Pathways (RCPs 2.6, 4.5, 6.0 and 8.5). Compared to 1960s values, we found an average increase in the UVI in 2100 (of 2-4%) in the tropical belt (30°N-30°S). For the mid-latitudes, we observed a 1.8 to 3.4 % increase in the Southern Hemisphere for RCP 2.6, 4.5 and 6.0, and found a 2.3% decrease in RCP 8.5. Higher increases in UVI are projected in the Northern Hemisphere except for RCP 8.5. At high latitudes, ozone recovery is well identified and induces a complete return of mean UVI levels to 1960 values for RCP 8.5 in the Southern Hemisphere. In the Northern Hemisphere, UVI levels in 2100 are higher by 0.5 to 5.5% for RCP 2.6, 4.5 and 6.0 and they are lower by 7.9% for RCP 8.5. We analysed the impacts of greenhouse gases (GHGs) and ozone-depleting substances (ODSs) on UVI from 1960 by comparing CCMI sensitivity simulations (1960-2100) with fixed GHGs or ODSs at their respective 1960 levels. As expected with ODS fixed at their 1960 levels, there is no large decrease in ozone levels and consequently no sudden increase in UVI levels. With fixed GHG, we observed a delayed return of ozone to 1960 values, with a corresponding pattern of change observed on UVI, and looking at the UVI difference between 2090s values and 1960s values, we found an 8 % increase in the tropical belt during the summer of each hemisphere. Finally we show that, while in the Southern Hemisphere the UVI is mainly driven by total ozone column, in the Northern Hemisphere both total ozone column and aerosol optical depth drive UVI levels, with aerosol optical depth having twice as much influence on the UVI as total ozone column does.
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http://dx.doi.org/10.5194/acp-2018-525 | DOI Listing |
ACS ES T Water
April 2025
Gerald May Department of Civil, Construction & Environmental Engineering, MSC01 1070, University of New Mexico, Albuquerque, New Mexico 87131, United States.
Understanding oxidized uranium [U(VI)] reactions with natural organic matter (NOM) is necessary to predict the solubility and mobility of U and NOM in waters from organically rich geologic uranium deposits influenced by natural and anthropogenic processes. Here, we investigated the changes in the chemical composition of NOM resulting from its reaction with U(VI) under acidic and neutral pH under controlled laboratory conditions. We employed a multianalytical approach, including X-ray photoelectron spectroscopy (XPS), Fourier transform ion cyclotron resonance-mass spectrometry (FTICR-MS), transmission electron microscopy (TEM), and X-ray absorption spectroscopy (XAS).
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August 2025
Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, Tehran, 14893-836, Iran.
The superior efficacy of synroc as an immobilization matrix for actinides in spent nuclear fuel has been extensively validated, positioning it as a leading candidate for long-term nuclear waste management. In this context, isotopic investigations of natural analogues are indispensable for optimizing synroc formulations, particularly regarding their capacity to incorporate and retain actinides and their decay products over geological timescales. In this study, a naturally occurring member of the pyrochlore supergroup was identified as betafite through integrated SEM, EMPA, and XRD analyses.
View Article and Find Full Text PDFRSC Adv
August 2025
Nuclear Materials Authority P.O. Box 530, El-Maadi Cairo Egypt
Carbon-free nuclear energy meets growing energy demand; uranium recycling enhances sustainability, economic, and environmental benefits. Herein, efficient three α-aminophosphonates-based sorbents were previously synthesized a one-pot method using distinct amine precursors (aniline, -phenylenediamine, anthranilic acid), yielding S-H, S-NH aminated, and S-COOH carboxylated, respectively enhanced aminophosphonate. Elemental analysis confirms three α-aminophosphonate sorbents (S-H, S-COOH, S-NH) with amine-dependent structures.
View Article and Find Full Text PDFAnal Methods
August 2025
School of Intelligent Materials and New Energy, Yuzhang Normal University, Nanchang 330031, China.
The 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (Br-PADAP) spectrophotometric method is widely employed for uranium (U(VI)) determination due to its high sensitivity. However, conventional protocols require toxic sodium fluoride as both a masking agent and a stabilizer, posing environmental and operational risks. To address this limitation, we developed an eco-friendly alternative utilizing low-toxicity sodium dodecyl sulfonate (SDS) for dual-functional masking and stabilization.
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August 2025
State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China.
Photocatalytic reduction of uranium from wastewater containing high concentrations of fluoride is crucial from both environmental and sustainability perspectives. However, the coordination of fluorine and uranyl ions to U(VI)-F complexes with high bond strengths poses challenges for photocatalysts. Electrostatic interactions induced by photocatalysis to dissociate U(VI)-F complexes provide an effective method for the extraction of uranium from wastewater containing fluorine.
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