Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Porphyrin-based Metal-Organic Frameworks (Por-MOFs) constitute a special branch of the wide MOF family that has proven its own value and high potential in different applications. In this mini-review the application of these materials as catalysts in oxidation reactions is highlighted.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273352 | PMC |
| http://dx.doi.org/10.3390/molecules21101348 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Water-Driven Oxygen and Nitric Oxide Release from Porphyrin- and Mn-Based Metal-Organic Framework Enables Accelerated Acute Wound Healing.
ACS Appl Bio Mater
September 2025
Division of Cardiovascular Surgery, Department of Surgery, College of Medicine, National Cheng Kung University Hospital, Tainan 704, Taiwan.
Medical gases, particularly oxygen and nitric oxide (NO), have attracted significant interest in clinical applications, notably wound healing, due to their role in enhancing cell proliferation, angiogenesis, and collagen deposition. However, the use of these gases has been limited by challenges such as inefficient gas delivery and potential toxicity to normal tissues. In this study, we elucidate a feasible approach using a porphyrin-based metal-organic framework (MOF), a unique material that shows immense potential for dual-gas-assisted wound healing.
View Article and Find Full Text PDFRational design of 2D-2D porphyrin metal-organic nanosheet/g-CN heterostructure for enhanced production of hydrogen under visible-light.
J Colloid Interface Sci
August 2025
Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, 140001, Punjab, India. Electronic address:
The development of heterojunction-based photocatalysts is a promising strategy to achieve enhanced green hydrogen (H) production by facilitating the competent separation of photo-induced charge carriers. In this context, two-dimensional (2D) metal-organic nanosheets (MONs) have garnered considerable attention owing to their unique properties of highly exposed active sites, ultrathin thickness, and large surface area. Especially, porphyrin-based 2D MONs have gained significant interest due to their optimum band structure and exceptional visible light harvesting properties.
View Article and Find Full Text PDFIncorporation of Cu within the ligand cavities of porphyrin-based MOFs for enhanced nonlinear optical performance.
Spectrochim Acta A Mol Biomol Spectrosc
August 2025
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, PR China.
Metal-organic frameworks (MOFs) constructed with porphyrins as organic ligands have attracted considerable attention due to their excellent nonlinear optical (NLO) properties. Developing innovative synthetic strategies and structural designs to improve the NLO response of porphyrin-based MOFs has become a prominent research area. In this paper, HTCPP MOF and CuTCPP MOF were synthesized by hydrothermal method with Co as metal node, and HTCPP and CuTCPP as ligands, respectively.
View Article and Find Full Text PDFHydroxamate Linkage Transformation in Porphyrin Functionalized Metal-Organic Frameworks.
Inorg Chem
September 2025
Department of Chemistry and Kavli Energy Nano Sciences Institute, University of California, Berkeley, California 94720, United States.
This study reports the discovery of five porphyrin-based metal-organic frameworks (MOFs) constructed from carboxylate, amide, and hydroxamate linkages. The MOFs, named the MOF-610 series (MOF-610-Co, MOF-610-Fe-1, and MOF-610-Fe-2), MOF-612, and MOF-614, were synthesized by implementing a high-throughput screening approach applying the porphyrin-based hydroxamic acid linker, 4,4',4″,4‴-(porphine-5,10,15,20-tetrayl)tetrakis(benzhydroxamic acid) (HPTBHA), in combination with an array of metal ions. After their synthesis, both the MOF-610 series and MOF-612 revealed in situ transformation of the hydroxamic acid linker, resulting in carboxylate or amide coordination species, while MOF-614 was able to retain the hydroxamate moiety.
View Article and Find Full Text PDFPorphyrin based hydrogen bond organic frameworks as enhanced ECL luminophore for the ultrasensitive detection of breast cancer 1 gene.
Anal Chim Acta
October 2025
College of Chemistry and Materials Sciences, College of Geography and Environmental Sciences, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua, 321004, China. Electronic address:
The demand for high-performance electrochemiluminescence (ECL) emitters in aqueous media continues to grow due to requirements for ultrasensitive biomedical detection. In this work, we report the synthesis of Zn (II) meso-tetra(4-carboxyphenyl) porphine (ZnTCPP) integrated with 4,4',4″-tricarboxytriphenylamine (TBA) for forming porphyrin-based hydrogen bond organic frameworks (ZnP-HOFs). The ZnP-HOFs showed strong ECL emission using KSO as coreactant, achieving a 5.
View Article and Find Full Text PDF