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Despite the high prominence of the perovskites BiFeO(3) and KNbO(3) the solid solution between the two has received little attention. We report a detailed neutron and synchrotron X-ray powder diffraction, and Raman spectroscopy study which demonstrates an R3c→P4mm→Amm2 series of structural phase transitions similar to that exhibited by the PbZrO(3)-PbTiO(3) solid solution.
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http://dx.doi.org/10.1039/c5dt00140d | DOI Listing |
Inorg Chem
September 2025
Institute of Inorganic and Analytical Chemistry, University of Münster, Corrensstraße 28/30, 48149 Münster, Germany.
Isovalent anion substitution has been shown to have a tremendous effect on the transport properties in lithium halide solid ionic conductors. Although sodium-ion solid state batteries based on chloride ionic conductors have recently gathered significant attention, investigations of anion substitution in sodium containing chlorides remain scarce. Here, we investigate the role of Br isoelectronic anion substitution in a perovskite-related compound with nominal composition of NaTaCl.
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September 2025
College of Science, Nanjing Forestry University, Nanjing, 210037, China.
Inspired by the rigid exoskeleton and elastic inner tissues of crustaceans, a bilayer gel integrating high-strength rigidity and soft cushioning with high interfacial adhesion (1060 ± 40 J m ) is developed via a stepwise solid-liquid phase crosslinking strategy. Herein, a prefrozen high-concentration polyvinyl alcohol (PVA) solution forms a solid-state structural framework, while a subsequently cast low-concentration PVA solution generates a flexible layer. Partial thawing of the frozen gel during casting triggers molecular chain interpenetration at the interface, synergistically enhanced by controlled molecular penetration, freeze-thaw cycles, and salt-induced crystallization.
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September 2025
Smart Material Research Laboratory, Department of Physics, Indian Institute of Technology Roorkee, Roorkee, 247667, India.
Achieving superior energy storage performance in dielectric materials under low electric fields remains a challenge. Most recent advancements require high fields that limit device applicability. Developing dielectric capacitors with high recoverable energy density (W), efficiency (η), and energy-storage coefficient (W/E) at low/moderate fields is critical for safer, compact, and durable electronics.
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September 2025
Inorganic Chemistry I Institute, Ruhr-Universität Bochum, Universitätsstrasse 150, 44801 Bochum, Germany.
Herein, we report a solid-state polycyclotrimerization of 1,4-diethynylbenzene using mechanochemical activation in a ball mill, yielding a highly porous and hydrophobic hyperbranched polymer (HBP) with a specific surface area of up to 570 m g. The reaction, catalyzed by Fe(hmds) and conducted under solvent-free conditions, was optimized by varying milling time and frequency. This method enables the efficient synthesis of insoluble, porous organic polymers with high yields (up to 95%) and offers an environmentally friendly alternative to traditional solution-based polymerizations.
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September 2025
Department of Materials Science and Engineering, Westlake University, Hangzhou 310030, PR China.
Uniform dispersion of carbon nanotubes in a polymer matrix is a prerequisite for high-performance nanotube-based composites. Here, we report an in situ polymerization route to synthesize a range of phenolic composites with high loading of single-wall carbon nanotubes (SWCNTs, >40 wt%) and continuously tunable viscoelasticity. SWCNTs can be directly and uniformly dispersed in cresols through noncovalent charge-transfer interactions without the need for surfactants, and further concentrated before in situ polymerization of the solvent molecules, yielding phenolic composites in the forms of conductive pastes, highly stretchy doughs, and hardened solids with high nanotube loading and much enhanced electrical conductivity (up to 2.
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