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By utilizing the phase change properties of vanadium dioxide (VO2), we have demonstrated the tuning of the electric and magnetic modes of split ring resonators (SRRs) simultaneously within the near IR range. The electric resonance wavelength is blue-shift about 73 nm while the magnetic resonance mode is red-shifted about 126 nm during the phase transition from insulating to metallic phases. Due to the hysteresis phenomenon of VO2 phase transition, both the electric and magnetic modes shifts are hysteretic. In addition to the frequency shift, the magnetic mode has a trend to vanish due to the fact that the metallic phase VO2 has the tendency to short the gap of SRR. We have also demonstrated the application of this active metamaterials in tunable surface-enhanced Raman scattering (SERS), for a fixed excitation laser wavelength, the Raman intensity can be altered significantly by tuning the electric mode frequency of SRR, which is accomplished by controlling the phase of VO2 with an accurate temperature control.
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http://dx.doi.org/10.1364/OE.22.002989 | DOI Listing |
J Am Chem Soc
September 2025
Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
CO electroreduction to produce fuels and chemicals is of great significance. Molecular catalysts offer valuable advantages in light of their well-defined active sites and tunable structural and electronic properties. However, their stability is often compromised by rigid conjugated structures.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2025
Department of Artificial Intelligence, Donders Center for Cognition, Radboud University, Nijmegen, GD 6525, Netherlands.
We present a geometric design rule for size-controlled clustering of self-propelled particles. We show that active particles that tend to rotate under an external force have an intrinsic, signed parameter with units of curvature which we call curvity, that can be derived from first principles. Experiments with robots and numerical simulations show that properties of individual robots (radius and curvity) control pair cohesion in a binary system, and the stability of flocking and self-limiting clustering in a swarm, with applications in metamaterials and in embodied decentralized control.
View Article and Find Full Text PDFNanomicro Lett
September 2025
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan, 250061, People's Republic of China.
CoS electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction (OER) activity, yet challenges remain in fabricating rechargeable lithium-oxygen batteries (LOBs) due to their poor OER performance, resulting from poor electrical conductivity and overly strong intermediate adsorption. In this work, fancy double heterojunctions on 1T/2H-MoS@CoS (1T/2H-MCS) were constructed derived from the charge donation from Co to Mo ions, thus inducing the phase transformation of MoS from 2H to 1T. The unique features of these double heterojunctions endow the 1T/2H-MCS with complementary catalysis during charging and discharging processes.
View Article and Find Full Text PDFAdv Mater
August 2025
Department of Laboratory Medicine, Southwest Hospital, Army Medical University (Third Military Medical University), Chongqing, 400038, China.
Precise, timely, and personalized in vivo thrombus monitoring is critical for improving the treatment effectiveness and clinical outcomes of cardiovascular diseases (CVDs). Terahertz (THz) spectroscopy has become increasingly important as a novel tool in biomedical engineering due to its rapid analysis ability, high temporal resolution, and label-free measurement modality. However, achieving high thrombus sensing performance in real blood environments remains a significant challenge.
View Article and Find Full Text PDFNat Commun
August 2025
Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China.
Untethered microrobots hold significant promise in fields such as bionics, biomedicine, and micromechanics. However, replicating the diverse movements of natural microorganisms in artificial microrobots presents a considerable challenge. This paper introduces a laser-based approach that utilizes lattice metamaterials to enhance the deformability of hydrogel-based microrobots, resulting in untethered light-driven lattice soft microrobots (LSMR).
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