Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(IV) starting materials.

Dalton Trans

Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.

Published: January 2014


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Article Abstract

The 1,2-dimethoxyethane (DME) solvento adducts of Np(iv) and Pu(iv) tetrachloride have been prepared and isolated in good and moderate yields, respectively, along with single-crystal structural determinations. These neutral molecules are expected to provide alternative synthetic pathways in the pursuit of non-aqueous and organometallic complexes.

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http://dx.doi.org/10.1039/c3dt53058bDOI Listing

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