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Top-contact organic field-effect transistors (OFETs) were fabricated by using a poly-3-hexyl-thiophene (P3HT) active layer. The characteristics of OFETs without and with the light-illumination were investigated. The experimental results indicate that the light has a great influence on the OFETs properties. After the light-illumination, the drain current and carrier mobility were increased, the threshold was decreased, and the on/off ratio was enhanced.
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http://dx.doi.org/10.1166/jnn.2010.2108 | DOI Listing |
Org Lett
September 2025
Istanbul Technical University, Chemistry Department, Maslak, Istanbul 34469, Turkey.
A donor-acceptor-donor type π-conjugated small molecule, , having an oligoether-functionalized azaisoindigo unit as an acceptor and triphenylamine units as donor groups was designed and synthesized. Its opto-electrochemical properties and charge transport applications were investigated. demonstrated p-type transport behavior with a maximum carrier mobility of 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Novosibirsk 630090, Russia.
While fluorene-containing materials are widely used in organic optoelectronics as bright emitters and hole semiconductors, their diazafluorene analogues have been poorly explored, though their nitrogen atoms could result in electron transport and bring sensory abilities. Here, we report the synthesis, characterization, and detailed study of a series of 4,5-diazafluorene-derivatives with different donor/acceptor substituents and organic semiconductors based on these molecules. The crystal structures of all the materials were solved by X-ray diffraction, indicating the presence of extensive π-stacking and anisotropic charge-transfer pathways.
View Article and Find Full Text PDFRSC Adv
August 2025
Chemistry Department, College of Science, King Khalid University Abha 61421 Saudi Arabia.
Hexa--hexabenzocoronene (HBC) and its derivatives have emerged as prominent polycyclic aromatic hydrocarbons (PAHs) due to their unique structural, electronic, and photophysical properties. This review provides a comprehensive overview of the synthetic strategies employed for the construction of HBC frameworks, ranging from traditional methods to recent advances that offer improved efficiency, regioselectivity, and structural diversity. The molecular architecture of HBCs, characterized by extended π-conjugation and planarity, contributes significantly to their stability and distinctive physical properties, including high charge-carrier mobility and tunable optical absorption.
View Article and Find Full Text PDFAdv Sci (Weinh)
August 2025
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China.
Precise patterning of small-molecule semiconductive crystals without external chemical additives remains a significant challenge. Herein, intrinsic photo-crosslinkable semiconductive small-molecule crystals (i-PSSCs) are designed and synthesized by associating [1]benzothieno[3,2-b]benzothiophene core with diacetylene-ended groups. The i-PSSCs undergo self-crosslinking directly upon UV light irradiation to yield micron-scale patterned crystalline films through a combination of photo-crosslinking and solvent rinsing.
View Article and Find Full Text PDFSci Adv
August 2025
College of Materials Science and Opto-Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences, Beijing 100049, China.
In human-robot interaction (HRI), the quality of user experience is paramount. Thus, developing strategies to tailor robotic responsiveness to user comfort zone is essential. However, current methods remain constrained by complex software and limited to unidirectional speed enhancement.
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