In this study, a novel nanocomposite was rationally engineered by embedding silver nanoparticles (AgNPs) into tannic acid-derived carbon spheres (Cs), followed by their distribution on graphene oxide (GO) sheets (AgNPs@Cs-TA@GO), aiming to enhance catalytic and antibacterial performance. The fabrication process was expedited using a microwave-assisted technique. The AgNPs@Cs-TA@GO nanocomposite with the core based on AgNPs with an average diameter of 21 nm showed significant peroxidase-like activity by oxidizing 3,3',5,5'-tetramethylbenzidine to its oxidized form in the presence of HO.
View Article and Find Full Text PDFThe biosynthesis of metal nanoparticles using natural extracts represents a significant advancement in quantitative analysis, as it effectively reduces nanoparticle aggregation, thereby enhancing the precision and dependability of analytical results. However, particle agglomeration of the nanoparticles continues to be a notable hurdle. In this study, for the first time, we addressed this issue by introducing gelatine into the synthesis of biogenic gold nanoparticles (AuNPs).
View Article and Find Full Text PDFA one-pot green synthesis approach was developed to fabricate Ag/Ni/FeO-activated carbon beads (Ag/Ni/MACB) using as a natural carbon precursor. Unlike conventional powdered catalysts, these millimeter-sized porous beads enable easy recovery and reusability, addressing a key limitation in heterogeneous Fenton systems. The FeO component facilitated Fenton-like reactions, while Ni and Ag nanoparticles synergistically enhanced electron transfer and visible-light absorption, significantly boosting photo-Fenton efficiency.
View Article and Find Full Text PDFA novel n-p FeO@ZnBiO (FZB) heterojunction with a unique 3D structure was fabricated in two simple steps to break down MB under visible light. First, the polymer gel combustion technique was employed to fabricate a 3D FeO framework. Next, a microwave-assisted precipitation approach was used to incorporate 3D ZnBiO flakes onto the framework surface.
View Article and Find Full Text PDFThe development of cost-effective and eco-friendly photocatalysts for wastewater treatment is crucial for addressing environmental pollution challenges. In this study, we report a novel MnO/ZnO nanocomposite supported on microalgae-derived activated carbon (AC) for the efficient photocatalytic degradation of rhodamine B (RhB) under visible light. FTIR analysis suggested interactions between the metal oxides and AC, while UV-vis DRS and PL studies revealed a reduced band gap and enhanced charge transfer in the composite, minimizing electron-hole recombination.
View Article and Find Full Text PDFThis study explores the synthesis, characterization, and photocatalytic properties of bismuth metal-organic framework (Bi-MOF) nanorods and their derivatives such as Ag/Bi-MOF and Ag/BiO. Bi-MOF nanorods exhibit significant photocatalytic activity under visible light, with the addition of silver (Ag) enhancing electron-hole pair separation and reducing their recombination. This leads to improved photocatalytic performance, particularly in the degradation of organic pollutants such as Rhodamine B (RhB) and Methylene Blue (MB).
View Article and Find Full Text PDFThe present study introduces FeO-coated lapatinib-labeled Sm nanoparticles (denoted as FeO@lapatinib-Sm) as a promising avenue for advancing breast cancer treatment. The radiolabeled nanoparticles combine various attributes, offering enhanced therapeutic precision. The integration of lapatinib confers therapeutic effects and targeted delivery.
View Article and Find Full Text PDFIn the present study, the biosynthesis of stable silver nanoparticles (BioAgNPs) was accomplished successfully for the first time by using an aqueous extract derived from the buds of (SN) as both a reducing and a stabilizing agent. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HR-TEM) investigations revealed that the biosynthesized BioAgNPs were predominantly spherical with an average size of 10-30 nm. It was found that the outstanding stability of the BioAgNPs colloidal solution was assigned to the additive effect of the surrounding protective organic layer and the highly negatively charged surface of the nanoparticles.
View Article and Find Full Text PDFWe present the in situ synthesis of silver nanoparticles (AgNPs) through ionotropic gelation utilizing the biodegradable saccharides lactose (Lac) and alginate (Alg). The lactose reduced silver ions to form AgNPs. The crystallite structure of the nanocomposite AgNPs@Lac/Alg, with a mean size of 4-6 nm, was confirmed by analytical techniques.
View Article and Find Full Text PDFCancer is a multifaceted disease that results from the complex interaction between genetic and environmental factors. Cancer is a mortal disease with the biggest clinical, societal, and economic burden. Research on better methods of the detection, diagnosis, and treatment of cancer is crucial.
View Article and Find Full Text PDFMicromachines (Basel)
January 2023
The first two-dimensional (2D) substance sparked a boom in research since this type of material showed potential promise for applications in field sensors. A class of 2D transition metal nitrides, carbides, and carbonitrides are referred to as MXenes. Following the 2011 synthesis of TiC from TiAlC, much research has been published.
View Article and Find Full Text PDFRoxb. is the largest genus of the Zingiberaceae family. A large number of species has been used as food and traditional medicines.
View Article and Find Full Text PDFNanosized zinc oxide is an intriguing material that can be applied in various fields. In this study, Ce doped ZnO nano-catalysts (Ce-ZnO) were synthesized by two different methods (, hydrothermal (Ce-ZnO-HT) and polymer gel combustion (Ce-ZnO-CB) methods) to compare their photodegradation efficiency. The prepared material characteristics were investigated using XRD, SEM, TEM, FTIR, UV-Vis, PL, XPS, EDS, and BET.
View Article and Find Full Text PDFBiogenic gold nanoparticles (AuNPs) have been extensively studied for the catalytic conversion of nitrophenols (NP) into aminophenols and the colorimetric quantification of heavy metal ions in aqueous solutions. However, the high self-agglomeration ability of colloidal nanoparticles is one of the major obstacles hindering their application. In the present study, we offered novel biogenic AuNPs synthesized by a green approach using Cistanche deserticola (CD) extract as a bioreducing agent and stabilized on poly(styrene-co-maleic anhydride) (PSMA).
View Article and Find Full Text PDFEnviron Chem Lett
April 2022
The release of pharmaceuticals into the environment induces adverse effects on the metabolism of humans and other living species, calling for advanced remediation methods. Conventional removal methods are often non-selective and cause secondary contamination. These issues may be partly solved by the use of recently-developped adsorbents such as molecularly imprinted polymers.
View Article and Find Full Text PDFThis study presents a simple and green approach for the synthesis of fruit extract capped gold nanoparticles (SG-AuNPs). The SG-AuNPs samples prepared under the optimized conditions were characterized by various techniques (UV-Vis, XRD, FTIR, HR-TEM, EDX, DLS). The biosynthesized nanoparticles were then studied for the reduction of 2-nitrophenol (2-NP) and 3-nitrophenols (3-NP) and for colorimetric detection of Pb ions.
View Article and Find Full Text PDFIn this article, a system for synthesizing Y-90 glass microspheres (Y-90-GM) was successfully designed in the Da Lat nuclear reactor (Vietnam), and the therapeutic effects of Y-90-GM on mice liver cancer cell line Hep3B were studied. The effects of synthesis factors, including heating time, heating temperature, gas flow rate, sample conduit length and diameter, were investigated to establish the optimal parameters. The size and shape of Y-90-GM were checked by field emission scanning electron microscope, and the radioactivity measurement was performed on a dosimeter.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2022
In this study, a simple, eco-friendly and low-cost approach was used to fabricate silver nanoparticles (AgNPs) from an aqueous extract of Gleditsia australis (GA) fruit. The nanoparticles synthesized in the optimal condition have an average size of 14 nm. The peroxidase-like activity of GA-AgNP in the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in combination with hydrogen peroxide (HO) was investigated.
View Article and Find Full Text PDFIt is vital to have high sensitivity in gas sensors to allow the exact detection of dangerous gases in the air and at room temperature. In this study, we used 2D MXenes and MoS materials to create a TiC-MoS composite with high metallic conductivity and a wholly functionalized surface for a significant signal. At room temperature, the TiC-MoS composite demonstrated clear signals, cyclic response curves to NO gas, and gas concentration-dependent.
View Article and Find Full Text PDFIn this study, we investigated two formulations of chitosan-Pluronic P123 with different folate ligand designation for targeted delivery of Paclitaxel (PTX), in which folic acid (FA) was directly conjugated to chitosan (FA-Cs-P123) or substituted onto P123 (Cs-P123-FA). The results showed that the FA content of Cs-P123-FA was determined at 0.71 wt/wt% which was significantly higher than that of FA-Cs-P123 (0.
View Article and Find Full Text PDFChemosphere
January 2022
In this study, novel biogenic silver (AgNPs) and gold nanoparticles (AuNPs) were developed using a green approach with Ganoderma lucidum (GL) extract. The optimization of synthesis conditions for the best outcomes was conducted. The prepared materials were characterized and their applicability in catalysis, antibacterial and chemical sensing was comprehensively evaluated.
View Article and Find Full Text PDFIn this study, a simple and environment-friendly method has been successfully applied for the production of silver nanoparticles (AgNPs) using Poria cocos extract. The reaction time of 60 min, the temperature of 90 °C, and silver ion concentration of 2.0 mM were identified as the best condition for the PC-AgNPs fabrication.
View Article and Find Full Text PDFChemosphere
December 2021
Photocatalytic hydrogen (H) generation derived by water has been considered as a renewable energy to solve environmental problems and global energy crises. Thus, it is necessary to explore the most effective photocatalysts by using multi-cocatalysts, due to an intimate interaction between different components. Therefore, we already synthesized the TiO/TiC/g-CN (TTC) photocatalyst from g-CN and TiC MXene via a calcination technique, and applied this composite for H evolution.
View Article and Find Full Text PDFNowadays, the widespread production and use of antibiotics have increased their presence in wastewater systems, posing a potential threat to the environment and human health. The development of advanced materials for treating antibiotics in wastewater has always received special attention. This study aimed to synthesize a novel CuO/FeO/MIL-101(Fe) nanocomposite and use it to degrade ciprofloxacin (CIP) antibiotics in an aqueous solution under visible light irradiation.
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