Lubricating additives are essential for enhancing the tribological properties of grease. The development of low-cost lubricant additives with excellent biodegradability is expected to be the prevailing trend for future advancements. In this study, biodegradable ultrafine β-tricalcium phosphate (β-TCP) was utilized to enhance the friction reduction, anti-wear and extreme pressure properties of barium complex greases at high temperatures.
View Article and Find Full Text PDFThe effects of shear degradation on the microstructures and properties of grease were investigated using a planetary ball mill to simulate a bearing shear zone on grease. The microstructure, cone penetration, colloidal stability, rheological properties noise properties, water washout characteristics and low-temperature torque of lithium grease were characterized. The microstructure of the initial lithium grease is a three-dimensional network structure formed by the uniform fibers.
View Article and Find Full Text PDFCarbohydr Polym
December 2022
The development of high-performance cellulose-based triboelectric nanogenerators (TENG) has been a subject widely concerned by researchers. Here, we prepared a composite aerogel film based on TEMPO-oxidized cellulose nanofiber (TOCN) and copper calcium titanate (CaCuTiO, CCTO) nanoparticles. Under their comprehensive effects of the enhanced dielectric performance, the TOCN/CCTO-20 composite film with 20 % CCTO content based TENG device showed the best output performance of an open circuit voltage of 152 V, a short circuit current of 33.
View Article and Find Full Text PDFIn order to develop a liquid oxygen-compatible (LOX-compatible) matrix resins for polymer-based fiber-reinforced composites, a novel phosphorus-containing imidazole derivative called VAD containing multifunctional groups was synthesized and used as a co-curing agent for epoxy resin (EP) with simultaneous LOX-compatibility and mechanical improvement. A phosphorus group was introduced into the EP to capture the free radicals generated during the pyrolysis of the polymer to improve LOX compatibility, and the trimethylene group was introduced as a flexible spacer to enhance the toughness of the cured material. In comparison to pure EP, the modified EP with only 2.
View Article and Find Full Text PDFSelf-healing ceramics have been researched at high temperatures, but few have been considered at lower temperatures. In this study, SiC-AlO-BC ceramic composite was compacted by spark plasma sintering (SPS). A Vickers indentation was introduced, and the cracks were healed between 600 °C and 800 °C in air.
View Article and Find Full Text PDFEmploying electrostatic self-assembly and free radical polymerization, the surface of SiO nanospheres was coated with poly(2-acrylamido-2-methylpropanesulfonic acid) (SiO@PAMPS) bearing strong electron withdrawing sulfonic and amide groups, enhancing the dissociation ability of the lithium salt of the liquid electrolyte and absorbing anions hydrogen bonds. After SiO@PAMPS nanospheres were introduced into the polypropylene (PP) membrane (SiO@PAMPS/PP), the electrolyte affinity and electrolyte uptake of the composite separators were significantly improved. The ionic conductivity of SiO@PAMPS/PP-18% (where 18% represents the concentration of the solution used for coating) soaked in liquid electrolyte was even 0.
View Article and Find Full Text PDFPolyethylene (PE) membranes coated with nano-AlO have been improved with water-dispersed poly(p-phenylene terephthamide) (PPTA). From the scanning electron microscope (SEM) images, it can be seen that a layer with a honeycombed porous structure is formed on the membrane. The thus-formed composite separator imbibed with the electrolyte solution has an ionic conductivity of 0.
View Article and Find Full Text PDFA novel polyethylene terephthalate nonwoven reinforced polypropylene composite separator (PET/PP) with high thermal stability and low thermal shrinkage characteristic is developed through a scalable production process. In the composite separator, the electronspun polyethylene terephthalate nonwoven layer improves the electrolyte affinity and can sustain as the barrier layer after the shutdown of the polypropylene layer. Due to its high ionic conductivity, the PET/PP separator shows an excellent discharge capacity.
View Article and Find Full Text PDFRobust and efficient catalysts for the oxygen reduction reaction (ORR) are required for the development of various energy storage and conversion devices. In this study, a durable and high-performance Fe C@graphene ORR catalyst has been developed by the carbonization of urea- and agar-modified Fe O nanorods. The influence of the carbonization temperature and annealing time on the activity and stability of the resulting Fe/C catalyst was studied in detail.
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