Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
A machine learning-designed "supramolecular armor" imparts exceptional stability to perovskite quantum dots. A guanidinium crosslinker reinforces a β-cyclodextrin layer, creating a robust yet permeable interface that enables direct contact sensing in challenging aqueous environments.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d5cc04384k | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Theoretical study of Lewis base passivation of p-type surface defects in I-Br mixed-halide tin perovskites.
J Chem Phys
September 2025
Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-Ku, Yokohama 236-0027, Kanagawa, Japan.
Perovskite-silicon tandem solar cells have attracted considerable attention owing to their high power conversion efficiency (PCE), which exceeds the limits of single-junction devices. This study focused on lead-free tin-based perovskites with iodine-bromine mixed anions. Bromide perovskites have a wide bandgap; therefore, they are promising light absorbers for perovskite-silicon tandem solar cells.
View Article and Find Full Text PDFMechanisms of Enhanced Efficiency and Stability in Perovskite Luminescence via Rb Interstitial Doping.
J Phys Chem Lett
September 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, P.R. China.
Metal halide perovskites have garnered significant attention due to their exceptional photoelectric properties. The alkali metal doping strategy has been demonstrated to effectively modulate grain size, control crystallization kinetics, and adjust band gap characteristics in perovskite. This study employs the first-principles calculations to reveal that the selection of alkali metal species and their corresponding doping methodologies exert markedly distinct influences on both the electronic properties and ion migration kinetics of CsPbBr perovskites.
View Article and Find Full Text PDFIonic Liquid Engineered Defect-Driven Green Emitting Zero-Dimensional CsPbBr Microdisks.
J Phys Chem Lett
September 2025
School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute Jatni, Khurda, Bhubaneswar 752050, Odisha, India.
Quantum-confined perovskites represent an emerging class of materials with great potential for optoelectronic applications. Specifically, zero-dimensional (0D) perovskites have garnered significant attention for their unique excitonic properties. However, achieving phase-pure, size-tunable 0D perovskite materials and gaining a clear understanding of their photophysical behavior remains challenging.
View Article and Find Full Text PDFHydrogen-Bond-Directed Chirality Transfer in Helical Polyacetylene-Perovskite-PDMS Elastomeric Films for Stretching-Tunable Multicolor Circularly Polarized Luminescence.
ACS Appl Mater Interfaces
September 2025
State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China.
Circularly polarized luminescence (CPL) has emerged as a critical technology for anticounterfeiting and optical display applications due to its unique chiroptical properties. We report a multicolor CPL-emitting elastomeric film (P37/PSK@SiO-PDMS) that synergistically combines chiral helical polyacetylene (P37) and a surface-engineered perovskite (PSK@SiO) through hydrogen-bond-directed assembly. Confinement within the PDMS matrix drives P37 to self-assemble into a chiral supramolecular structure through hydrogen bonding, inducing a chiroptical inversion.
View Article and Find Full Text PDFMachine learning-guided design of a supramolecular armor for stable and functional perovskite quantum dots.
Chem Commun (Camb)
September 2025
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, P. R. China.
A machine learning-designed "supramolecular armor" imparts exceptional stability to perovskite quantum dots. A guanidinium crosslinker reinforces a β-cyclodextrin layer, creating a robust yet permeable interface that enables direct contact sensing in challenging aqueous environments.
View Article and Find Full Text PDF