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Environmentally friendly food packaging has emerged as a viable strategy to replace traditional plastic films. In this study, eugenol Pickering emulsion was constructed with konjac glucomannan (KGM) and tragacanth gum (GT) as stabilizers, and was introduced into the KGM/chitosan (CS) composite film by electrostatic action to develop a new type of active packaging film. Interfacial characterization revealed optimal emulsion stability at a 1:5 KGM-to-GT mass ratio. Compared to pure KGM and CS films, the KC-KT@EUG films maintained excellent flexibility while demonstrating superior WVP, OP, and UV barrier properties and soil degradability. FTIR and XRD confirmed successful component integration, TGA indicated reduced thermal stability, and SEM showed homogeneous emulsion dispersion in the film matrix. The KC-KT@EUG films exhibited remarkable antimicrobial and antioxidant activities, significantly outperforming PE films (p < 0.05) in decay rate, weight loss, firmness, and soluble solids of blueberries over 9 days of storage. Consequently, shelf life was extended by 10 days, demonstrating the films' great potential for fresh-produce preservation.
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http://dx.doi.org/10.1016/j.carbpol.2025.124117 | DOI Listing |
J Chem Phys
September 2025
Center of Materials and Nanotechnologies (CEMNAT), Faculty of Chemical Technology, University of Pardubice, nam. Cs legii 565, 530 02 Pardubice, Czech Republic.
Joint direct microscopy-calorimetry measurements of crystal growth were performed for a 60 nm amorphous Sb2S3 film deposited either on a Kapton foil or on a soda-lime glass. Calorimetric crystallization proceeded in two steps, originating either from mechanical and stress-induced defects (230-275 °C) or from homogeneously formed nuclei (255-310 °C); both processes exhibited an identical activation energy of 200 kJ mol-1. At temperatures <230 °C, a Sb2O3 crystalline phase formed along the rhombohedral Sb2S3 structure.
View Article and Find Full Text PDFAdv Mater
September 2025
Key Lab of Artificial Micro- and Nano-Structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan, 430072, China.
Sequential deposition technique is widely used to fabricate perovskite films with large grain size in perovskite solar cells (PSCs). Residual lead halide (PbI) in the perovskite film tends to be decomposed into metallic lead (Pb) under long-term heating or light soaking. Here, a chiral levetiracetam (LEV) dopant containing α-amide and pyrrolidone groups is introduced into the PbI precursor solution.
View Article and Find Full Text PDFNanoscale Adv
August 2025
Department of Metallurgical and Materials Engineering, Faculty of Engineering, University of Dokuz Eylül İzmir Turkey.
Thin films of CuSn Gd S were prepared on soda-lime glass substrates using spin coating in a sulfur-rich environment. We investigated how doping CuSnS with gadolinium (Gd) affected its structural, morphological, and optical properties using X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), and UV-Vis spectroscopy. XRD showed that all samples had a polycrystalline monoclinic structure, while FE-SEM revealed a mix of spherical and polygon-shaped grains.
View Article and Find Full Text PDFChem Sci
August 2025
State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, School of Chemistry and Chemical Engineering, Henan Normal University 46 Jianshe Road Xinxiang 453007 China +86
The construction of polymer-based photoactivated room-temperature phosphorescence systems remains a prominent research focus, yet the development of ultrafast activated systems under ambient conditions continues to pose a challenge. In this study, cyclized phenothiazine derivatives bearing diverse substituents are synthesized and incorporated into an amorphous polyvinyl alcohol (PVA) matrix, resulting in significantly enhanced dynamic photoactivation characteristics compared with those of their pristine monomeric counterparts. Under ambient conditions and 2 s irradiation, the lifetime and quantum yield of C[4]PTZ-OH@PVA increase by factors of 1.
View Article and Find Full Text PDFFood Sci Biotechnol
October 2025
Department of Food Technology, Faculty of Agriculture, "Ion Ionescu de La Brad, Iasi University of Life Sciences, 3 Mihail Sadoveanu Alley, 700490 Iasi, Romania.
Unlabelled: Packaging can be a major source of food contamination. To ensure the safety of the final packaging for the food industry, it is imperative to undertake a thorough assessment of potential contaminants that may come into contact with the food. This examination begins with evaluating the materials used in the production process of the packaging.
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