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Currently, flexible perovskite solar cells (FPSCs) have achieved power conversion efficiencies exceeding 26% at the laboratory scale. Recently, roll-to-roll (R2R) fabrication has emerged as a highly promising solution for the low-cost, large-scale production of FPSCs. However, transitioning from laboratory research to industrial production remains an urgent and critical challenge. This review systematically analyzes various fabrication techniques for FPSCs. Special emphasis is then placed on R2R-compatible processes for perovskite layer deposition, as well as other functional layers, including electron transport layers, hole transport layers, and electrodes. Finally, a forward-looking perspective is presented on the commercialization of FPSCs, highlighting the current limitations of R2R manufacturing and proposing feasible strategies to overcome technical bottlenecks, thereby accelerating the industrialization of high-efficiency FPSCs.
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http://dx.doi.org/10.1021/acsami.5c14588 | DOI Listing |
Adv Mater
September 2025
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China.
Perovskite materials have revolutionized optoelectronics by virtue of their tunable bandgaps, exceptional optoelectronic properties, and structural flexibility. Notably, the state-of-the-art performance of perovskite solar cells has reached 27%, making perovskite materials a promising candidate for next-generation photovoltaic technology. Although numerous reviews regarding perovskite materials have been published, the existing reviews generally focus on individual material systems (e.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
National Laboratory of Solid State Microstructures, School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
For optoelectronic devices based on lead-halide perovskites and other semiconductors, a comprehensive understanding of the electric field influences on the carrier transport characteristics is critical to the optimization of their practical performances. To fulfill this challenging goal, here we have employed photoluminescence spatial image and transient absorption microscopy measurements on an individual CsPbBr microplate biased at external voltages in an Au/CsPbBr/Au device. At the subpicosecond time scale, some photogenerated excitons are dissociated into free electrons and holes that drift toward the electrodes to leave behind unfilled defect sites, which are capable of scattering the residual excitons to yield a reduced diffusion coefficient.
View Article and Find Full Text PDFAtomic layer deposition (ALD) enables an excellent surface coverage and uniformity in the preparation of large-area metal-oxide thin films. In particular, ALD-processed SnO has demonstrated great potential as an electron transport layer in flexible perovskite solar cells (PSCs) and tandem modules. However, the poor electrical conductivities and surface wettabilities of amorphous SnO remain critical challenges for commercialization.
View Article and Find Full Text PDFThe functionalization of thin, flexible glass with piezoelectric oxides is a pathway toward transparent electromechanical devices. The crystallization of lead zirconate titanate thin films on thick, rigid glass is previously demonstrated using flash lamp annealing to selectively anneal the films, without damaging the substrates. In this work, a 2-step process suitable for Schott AF 32 eco glass and Corning Willow glass is developed, both 100 μm thick, the latter of which is compatible with roll-to-roll processes.
View Article and Find Full Text PDFAdv Mater
September 2025
Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Boulevard, Shenzhen, 518055, China.
Phase segregation remains one of the most critical challenges limiting the performance and long-term operational stability of wide-bandgap perovskite solar cells (PSCs). This issue is especially pronounced in 1.84 eV wide-bandgap (WBG) perovskites, where severe halide phase segregation leads to compositional heterogeneity and accelerated device degradation.
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