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A magnesium oxide (MgO) coating strategy is proposed for improving the cobalt-free high-nickel LiNiMnO cathode. It is revealed that a MgO coating can stabilize reversible Ni/Ni redox and suppress structural degradation. The MgO coated LiNiMnO exhibits a promising capacity retention of 66.67% after 1000 cycles at 1C rate in a wide voltage range of 2.8-4.4 V.
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http://dx.doi.org/10.1039/d5cc03625a | DOI Listing |
J Am Chem Soc
September 2025
Inorganic Materials Chemistry, Ruhr University Bochum, Universitätsstr. 150, 44801 Bochum, Germany.
Magnesium(II) oxide (MgO) is a versatile material that is appealing for a wide range of applications including electronics and biocompatible coatings, as pharmaceutics, and gas barrier layers (GBLs). The growth of MgO films at low temperatures is required for these applications which can be enabled by atomic layer deposition (ALD). However, the chemistry of ALD precursors reported to date for MgO is limited and there are no suitable chemistries for low temperature deposition on sensitive substrates.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
Department of Materials Science, Fudan University, Shanghai 200433, PR China.
A magnesium oxide (MgO) coating strategy is proposed for improving the cobalt-free high-nickel LiNiMnO cathode. It is revealed that a MgO coating can stabilize reversible Ni/Ni redox and suppress structural degradation. The MgO coated LiNiMnO exhibits a promising capacity retention of 66.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Defence Research Institute, Universiti Pertahanan Nasional Malaysia, Kem Perdana Sungai Besi, Kuala Lumpur 57000, Malaysia.
Cellulose nanocellulose (CNPs) is a virtual inexhaustible source of feedstock meeting the increasing demand for green, biocompatible products and ideal candidates for nanocomposites preparation for various application such as in packaging, biomedical devices, electronics, water treatment, energy storage devices and also in electronics application. However, integration of CNPs based nanocomposite into nanofluid application has received little attention which presents a clear research gap. As a result, this study used a bio-based functionalized sodium carboxymethyl nanocellulose (ACNPs) synthesis from oil palm empty fruit bunch (OPEFB) as a template, to synthesize hybrid nanocomposites with metal oxide (MONPs) at varying ACNP-to-MONP weight ratio.
View Article and Find Full Text PDFJ Mater Sci Mater Med
July 2025
Department of Materials Engineering, Babol Noshirvani University of Technology, Shariati Avenue, Babol, 47148-71167, Iran.
In this study, an innovative hydroxyapatite-titanium-magnesium oxide composite coating was successfully fabricated on TiAlV alloy using plasma spraying to enhance its mechanical and corrosion performance for biomedical applications. Granulation of nano-sized HA powder (~100 ± 20 nm) produced spherical agglomerates in the range of 5-20 µm, ensuring suitable flowability for uniform coating deposition. SEM analyses confirmed dense and crack-minimized layers for both pure HA (~105 µm thick) and composite (~98 µm thick) coatings.
View Article and Find Full Text PDFR Soc Open Sci
July 2025
Japan Advanced Institute of Science and Technology (JAIST), Nomi, Ishikawa, Japan.
Conventional cancer therapies are frequently limited by systemic toxicity and inadequate selectivity, necessitating the development of novel therapeutic approaches. Nanotechnology has emerged as a promising platform for achieving targeted and drug-free cancer treatments. In this study, we report a drug-free anti-cancer strategy based on cationic polymer-coated magnesium oxide nanoparticles (MgO NPs).
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