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Article Abstract
We presented a Selectfluor-mediated direct oxidative -arylation of -acyl sulfenamides with naphthols via an oxidation to sulfinimidoyl fluoride/nucleophilic substitution cascade process. Notably, this methodology is time-efficient, operationally safe, and easily scalable without requiring prefunctionalized arenes or transition-metal catalysts. It exhibits excellent functional-group compatibility, providing a series of sulfilimines in good to high yields (40 examples, up to 95%).
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