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Municipal solid waste incineration (MSWI) fly ash partially replaces the cement-solidified sediment as intermediate cover materials in landfills, which can realize the resource utilization of MSWI fly ash and sediment. In this study, durability of MSWI fly ash solidified sediment as intermediate cover materials in landfills under drying-wetting cycles was investigated through various laboratory tests including unconfined compressive strength (UCS), direct shear (DS), Scanning Electron Microscope-Energy Dispersive Spectrometer (SEM-EDS), X-ray diffraction (XRD), and thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). Results revealed that the UCS, internal friction angle (φ), and cohesion (c) increased with the number of drying-wetting cycles and the decreased of MSWI fly ash replacement ratio. The increase of φ and c improved the stability of landfill, and the durability index (Δ) of the samples after 5th drying-wetting cycles were greater than 1. The dry-wet cycle will cause the pores of the sample to increase. Additionally, calcium carbonate precipitation was also generated during the treatment, indicating that the solidified sediment not only underwent hydration reaction and carbonation reaction but also dry matrix contraction reaction in the process. Both reactions facilitated growth of strength and increase in resistance of MSWI fly ash solidified sediment to drying and wetting cycles. These findings suggest that MSWI fly ash solidified sediment can serve as a green and sustainable intermediate cover material in landfills.
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http://dx.doi.org/10.1016/j.jenvman.2025.126760 | DOI Listing |
J Environ Manage
September 2025
Interdisciplinary Research Center for Construction and Building Materials, Department of Materials Science and Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia.
The disposal of municipal solid waste incineration fly ashes (MSWI-FA) is complicated by soluble chlorides, which increase the risk of heavy metals (HMs) leaching toxicity and hinder the further use of remediated MSWI-FA. In this study, the self-assembly potentiality of magnesium oxychloride cement (MOC) in geopolymerization was explored and utilized to enhance the solidification/stabilization (S/S) of the MSWI-FA. The MOC-self-assembled geopolymerization kinetics can be suitably described by the JMAK model.
View Article and Find Full Text PDFToxics
August 2025
School of Engineering, Hangzhou Normal University, Hangzhou 310018, China.
Municipal solid waste incineration fly ash (MSWI FA) is recognized as a hazardous solid waste due to its enrichment in toxic heavy metals and high leaching potential. This review systematically summarizes the current understanding of heavy metal occurrence in MSWI FA and associated environmental risks. Solidification and stabilization methods, such as cement-based curing and chemical immobilization, are widely applied due to their cost-effectiveness and operability, though their long-term stability and recovery potential remain limited.
View Article and Find Full Text PDFJ Environ Manage
August 2025
University of Bologna, Department of Biological, Geological and Environmental Sciences (BiGeA), Piazza di Porta San Donato, 1, Bologna, Italy; National Research Council of Italy (CNR), Department of Scienze Del Sistema Terra e Tecnologie per l'Ambiente, Marine science institute (ISMAR), Napoli Resea
Municipal Solid Waste Incineration (MSWI) plants pose significant environmental concerns, generating solid by-products, namely Fly Ash (FA) and Bottom Ash (BA). These MSWI residues have received attention due to the presence of valuable elements, Potentially Toxic Elements (PTE), and other contaminants. Radionuclide detection is also critical because they can concentrate in incineration ashes to pose a radiological hazard.
View Article and Find Full Text PDFJ Hazard Mater
August 2025
Institute of Mineral Resources, University of Science and Technology Beijing, Beijing 100083, China.
The preparation of solidified materials using biochar (BC) and MSWI fly ash (FA) promotes pollutant remediation and the resource utilization of solid waste. However, studies on the quantitative risk assessment of BC-enhanced MSWI FA/bottom ash (BA)-coal FA-based cementitious materials (CBFM) and the synchronous immobilization mechanisms of heavy metals and anions are still limited. This study used multiple leaching methods and the RAC/OPTI model to evaluate the leaching behavior and environmental risk of MSWI FA/CBFM under various pH conditions.
View Article and Find Full Text PDFEnviron Res
August 2025
School of Environment, Tsinghua University, Beijing, 100084, China; State Key Laboratory of Iron and Steel Industry Environmental Protection, 17 Xiangrui Street, Daxing District, Beijing, 102600, China. Electronic address:
Washing and thermal treatment are commonly employed to control hazardous components such as chlorides and heavy metals in incineration fly ash (FA). However, the fate and transformation of polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) during these processes have often been assumed rather than explicitly elucidated. In this study, the occurrence, migration, and degradation mechanisms of PCDD/Fs during sequential washing and thermal treatment were systematically investigated.
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