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The rare-earth α-pyrochlore iridates are a prospective class of conducting frustrated magnets where electronic correlations, large spin-orbit coupling, and geometrical frustration interplay, leading to a rich set of magnetic and electronic phases. Despite their intriguing properties, the magnetic order and excitations in this fundamental class of topological quantum materials remain poorly understood due to challenges in growing large single crystals and insufficient microscopic information on their temperature-dependent phases. Here, by combining state-of-the-art thin-film synthesis, resonant elastic and inelastic X-ray scattering, spin wave analysis, and dynamical spin susceptibility calculations, we unequivocally reveal the presence of spectrally sharp, gapped magnetic excitations in YIrO that surprisingly persist well above the Néel transition temperature, signaling the presence of a quasi-universal regime connected to fluctuations on frustrated lattices. This finding implies the existence of a highly unusual cooperative paramagnetic (CP) phase above the ordering temperature and offers an explanation for the puzzling high-temperature magnetic behavior observed across the family of metallic pyrochlore crystals. Understanding such magnetic excitations at technologically relevant temperatures opens up possibilities for novel topological spintronic devices.
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http://dx.doi.org/10.1038/s41467-025-61752-8 | DOI Listing |
Nat Commun
September 2025
Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, Berlin, Germany.
Light-induced magnetisation switching is one of the most intriguing and promising areas where an ultrafast phenomenon can be utilised in technological applications. So far, experiment and theory have considered the origin of all-optical helicity-independent magnetisation switching (AO-HIS) in individual magnetic films only as a microscopically local, thermally-driven process of angular momentum transfer between different subsystems. Here, we demonstrate that this local picture is insufficient and that AO-HIS must also be regarded as a spatially inhomogeneous process along the depth within a few-nanometre thin magnetic layer.
View Article and Find Full Text PDFNeuroimage
September 2025
Center for Bioelectric Interfaces, Higher School of Economics, Moscow, Russia; LLC "Life Improvement by Future Technologies Center", Moscow, Russia; AIRI, Artificial Intelligence Research Institute, Moscow, Russia. Electronic address:
Objective: Upcoming neuroscientific research will require bidirectional and context dependent interaction with nervous tissue. To facilitate the future neuroscientific discoveries we have created HarPULL, a genuinely real-time system for tracking oscillatory brain state.
Approach: The HarPULL technology ensures reliable, accurate and affordable real-time phase and amplitude tracking based on the state-space estimation framework operationalized by Kalman filtering.
J Am Chem Soc
September 2025
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307, United States.
We report the first paramagnetic boron tetraradical, comprising four boraphenanthrene-type units with boryl radical centers bridged by a central tetraphenylethene (TPE) linker. With strongly π-accepting and sterically demanding cyclic(alkyl)(amino) carbene ligands (), spin densities localize on the boron-carbene fragments (92%), consistent with a true boron-centered tetraradical. Magnetic measurements of reveal minimal spin-spin coupling, consistent with four noninteracting = 1/2 centers.
View Article and Find Full Text PDFLight Sci Appl
September 2025
Department of Materials Science and Engineering, Centre for Functional Photonics, and Hong Kong Branch of National Precious Metals Material Engineering Research Centre, City University of Hong Kong, Hong Kong, China.
Observation of the second-harmonic generation (SHG) from subwavelength metallic structures is often hindered by the interrelations of higher-order multipolar contributions. In particular, the magnetic Lorentz contribution to SHG is often neglected due to the ineffective magnetic field enhancement in electrically resonant structures. Here, we demonstrate a strong Lorentz-driven SHG output at the plasmon-induced magnetic dipolar resonance in inversion-symmetry-broken plasmonic nanocavities.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Nantes Université, CNRS, CEISAM UMR 6230, F-44000 Nantes, France.
Owing to their unique combination of magnetic and optical properties, luminescent polychlorinated radicals are promising candidates for advanced applications in both optoelectronics and quantum technologies. In this study, we employ the lineshape formalism within a computational protocol based on time-dependent density functional theory (TD-DFT) to investigate the excited-state properties of six representative members of this family presenting different sizes and excited-state characters. We explore a wide range of density functionals, applying or not the Tamm-Dancoff approximation (TDA), combined with different vibronic models, namely, the vertical gradient (VG), vertical Hessian (VH), and adiabatic Hessian (AH), as well as dipole moment expansions using the Franck-Condon (FC) and Herzberg-Teller (HT) approximations.
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