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Background/purpose: The esthetic performance of dental zirconia may be affected by both material composition and environmental exposure. This study aimed to evaluate how different aging conditions-hydrothermal aging and thermal cycling-influenced the optical properties of dental zirconia containing varying yttria concentrations (3Y-TZP, 4Y-TZP, and 5Y-TZP) in coffee and tea.
Materials And Methods: A total of 120 zirconia specimens were prepared using three yttria concentrations. Each group was subjected to four artificial aging conditions: storage in coffee or tea at 37 °C for 1 and 6 months (hydrothermal aging), or 10,000 and 50,000 cycles of thermal cycling between 5 °C and 55 °C. Optical parameters (L∗, a∗, b∗) and color differences (ΔE) were measured using a spectrophotometer and calculated using the CIEDE2000 formula. Data were analyzed using ANOVA and Tukey's HSD test (α = 0.05).
Results: Zirconia with higher yttria content exhibited more pronounced color changes ( < 0.001). Aging in tea resulted in minimal color variation regardless of yttria content or aging mode. In coffee, the ΔE values of the HT (3Y-TZP), ST (4Y-TZP), and XT (5Y-TZP) groups ranged from 3.5, 7.0 and 8.5, respectively ( < 0.0001). In tea, the values ranged from 1.1 for both HT and ST, and from 3.1 for XT ( < 0.0001).
Conclusion: Both yttria concentration and aging conditions significantly influenced the color stability of zirconia. Hydrothermal aging had a greater impact than thermal cycling, especially in coffee. These findings suggest that material composition and exposure environment should be carefully considered when selecting zirconia for esthetic dental restorations.
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http://dx.doi.org/10.1016/j.jds.2025.04.017 | DOI Listing |
Materials (Basel)
August 2025
Departamento de Ingeniería Mecánica, Energética y de los Materiales, Universidad de Extremadura, Avenida de Elvas, s/n, 06006 Badajoz, Spain.
This study focuses on optimizing a sol-gel based electrodeposition-sintering process for producing yttria-stabilized zirconia (YSZ) ceramic coatings on stainless steel substrates. Four key process variables-precursor concentration, current density, sintering time, and temperature-were evaluated in terms of two response variables: R (electrodeposition yield) and S (sintering yield). A fractional factorial design was used to reduce the number of experiments while enabling robust statistical modeling.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Suzhou Nano Science and Technology, National-Local Joint Engineering Laboratory for Absorptive Materials and Technologies in Environmental Protection, National Center for International Research on In
The electrosynthesis of hydrogen peroxide (HO), with renewable electricity, air, and water as inputs, offers a sustainable alternative to the conventional anthraquinone process. Performing HO electrosynthesis in concentrated acid offers advantages in functionality and energy efficiency over alkaline media yet is currently limited by short longevity. Here, we first investigate the origins of performance loss of oxidized carbon, a proven catalyst for HO electrosynthesis, and observe its gradual reduction to pristine carbon during acidic electrolysis.
View Article and Find Full Text PDFJ Esthet Restor Dent
July 2025
Department of General Practice, School of Dentistry, Virginia Commonwealth University, Richmond, Virginia, USA.
Statement Of Problem: Erbium-doped yttrium aluminum garnet (Er:YAG) laser debonding has recently emerged as an alternative method for removing zirconia and lithium disilicate restorations. The optical and mechanical properties are critical factors influencing the success of ceramic restorations. However, limited research has focused on how the Er:YAG laser impacts the optical and mechanical properties of these ceramic materials.
View Article and Find Full Text PDFJ Dent Sci
July 2025
Department of Dentistry, Wan Fang Hospital, Taipei Medical University, Taipei, Taiwan.
Background/purpose: The esthetic performance of dental zirconia may be affected by both material composition and environmental exposure. This study aimed to evaluate how different aging conditions-hydrothermal aging and thermal cycling-influenced the optical properties of dental zirconia containing varying yttria concentrations (3Y-TZP, 4Y-TZP, and 5Y-TZP) in coffee and tea.
Materials And Methods: A total of 120 zirconia specimens were prepared using three yttria concentrations.
Dent J (Basel)
June 2025
Faculty of Dentistry, George Emil Palade University of Medicine, Pharmacy, Science, and Technology of Targu Mures, 38 Gheorghe Marinescu Street, 540142 Târgu Mureș, Romania.
This study investigates the chemical structure and molecular interactions in 3D-printed dental resins reinforced with varying concentrations of Yttria-Stabilized Zirconia (YSZ) nanoparticles, using Fourier-Transform Infrared Spectroscopy (FTIR) to assess the compatibility and bonding behavior at the molecular level. Three groups of 3D-printed methacrylate-based resin discs were fabricated: a control (0% YSZ), and experimental groups reinforced with 1% and 3% YSZ nanoparticles. Samples were produced using Digital Light Processing (DLP) technology and post-processed under standardized conditions.
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