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Chiral quantum interfaces are a compelling platform for the mapping of spin to path, offering innovative strategies for chiral single photon routing. Glide-plane photonic crystal waveguide (GPW) embedded with quantum dots (QDs) enables both Purcell enhancement and chiral coupling, making it a promising candidate for chiral quantum interfaces. However, the continuous band structure in the GPW enables the chiral quantum interface that radiates bidirectionally. Here, we demonstrate a unidirectional chiral quantum interface through the coupling of an InAs QD to the spin-locking mode of a single-mode GaAs microring resonator. This chiral coupling enables dynamic control over the emission direction and spin of the QD through modulation of the magnetic field. The interface exhibits a near-unity field-independent cavity-assisted chiral contrast, a Purcell factor of 1.58 and a single-photon purity of (0) = 0.0795 ± 0.009. This capability significantly expands the application scope of chiral quantum optics and develops scalable networks based on chiral quantum photonics.
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http://dx.doi.org/10.1021/acs.nanolett.5c02598 | DOI Listing |
Nanoscale
September 2025
St. Petersburg State University, 199034 St. Petersburg, Russia.
Using angle-resolved photoemission spectroscopy (ARPES) with spin resolution, scanning tunneling microscopy/spectroscopy (STM/STS) and density functional theory (DFT) methods, we study the electronic structure of graphene-covered and bare Au/Co(0001) systems and reveal intriguing features, arising from the ferrimagnetic order in graphene and the underlying gold monolayer. In particular, a spin-polarized Dirac-cone-like state, intrinsically related to the induced magnetization of Au, was discovered at point. We have obtained a good agreement between experiment and theory for bare and graphene-covered Au/Co(0001) and have proven that both Au ferrimagnetism and the Dirac-cone-like band are intimately linked to the triangular loop dislocations present at the Au/Co interface.
View Article and Find Full Text PDFNat Prod Res
September 2025
Key Laboratory of Plant Resources and Chemistry in Arid Regions, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, P. R. China.
Chemical investigations of the -butanol extract of the roots of were carried out using column chromatography, flash, semi-preparative HPLC, and chiral HPLC. Five unidentified compounds, including two prenylated coumarin glucosides, two prenylated furanocoumarin glucosides, and a benzofuran glucoside, together with twelve known compounds, were isolated from the -butanol fraction of extract. The structures of these compounds were identified by HRMS, NMR, UV, ECD in combination with quantum chemical calculations, and comparison with the literature.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China.
Circularly polarized luminescence (CPL) has emerged as a critical technology for anticounterfeiting and optical display applications due to its unique chiroptical properties. We report a multicolor CPL-emitting elastomeric film (P37/PSK@SiO-PDMS) that synergistically combines chiral helical polyacetylene (P37) and a surface-engineered perovskite (PSK@SiO) through hydrogen-bond-directed assembly. Confinement within the PDMS matrix drives P37 to self-assemble into a chiral supramolecular structure through hydrogen bonding, inducing a chiroptical inversion.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
CFisUC, Department of Physics, University of Coimbra, 3004-516, Coimbra, Portugal.
With the goal of manipulating (bio)chemical processes, photoswitches emerge as important assets in molecular nanotechnology. To guide synthetic strategies toward increasingly more efficient systems, conformational dynamics studies performed with atomic rigor are in demand, particularly if this information can be extracted with control over the size of a perturbing solvation layer. Here, we use jet-cooled rotational spectroscopy and quantum chemistry calculations to unravel the structure and micro-hydration dynamics of a prototype photoswitch.
View Article and Find Full Text PDFSci Adv
September 2025
Materials Department, University of California, Santa Barbara, CA 93106-5050, USA.
Thermoelectric responses in two-dimensional electron gases subjected to magnetic fields have the potential to provide unique information about quasiparticle statistics. In this study, we show that chiral edge states play a key role in thermoelectric Hall bar measurements by completely controlling the direction of the internal thermal gradient. To this end, we perform measurements of the magnetothermoelectric responses of cadmium arsenide quantum wells.
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