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This study investigates the current state of microplastic (MP) pollution and ecological risks in the middle and lower reaches of the Yellow River, focusing on the Henan section. Using the advanced MultiMP risk assessment method, both surface water and sediment environments were comprehensively evaluated. Results indicate that MPs were detected in both environments, with surface water abundance ranging from 3.35 to 12.6 n/L and sediment abundance from 206 to 1647 n/kg. In terms of the main characteristics of MPs, the most common particle size ranged from 25 to 150 μm; fibrous shapes were the most abundant in both surface water and sediments; transparent MPs had the highest proportion in terms of color; and in terms of polymer composition, polyethylene (PE) and polypropylene (PP) were the main polymers found in surface water, while PE and polyethylene terephthalate (PET) were more common in sediments. Environmental factors influencing the MP distribution were also investigated. The abundance of MPs in surface water was closely related to total phosphorus (WTP) and total nitrogen (WTN), while the abundance of MPs in sediments was closely associated with the sediment particle size. MultiMP assessment results show medium risk for surface water and high risk for most sediments in the Henan section of the Yellow River Basin, with differing main factors affecting risk levels in the two environments. These findings fill regional research gaps and provide data support and theoretical foundations for effective MP pollution management in the Yellow River Basin.
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http://dx.doi.org/10.1016/j.jhazmat.2025.139059 | DOI Listing |
Langmuir
September 2025
Federal University of São Paulo, Laboratory of Hybrid Materials, Diadema, São Paulo 09913-030, Brazil.
This study demonstrates the successful fabrication of nanostructured Langmuir-Blodgett (LB) films combining the conjugated copolymer poly(9,9-dioctylfluorene--3,4-ethylenedioxythiophene) (PDOF--PEDOT) with spherical and triangular silver nanoparticles (AgNP). The LB technique allowed precise control over the molecular arrangement and distribution of the nanoparticles at the air-water interface, resulting in compact, reproducible and structurally ordered nanocomposite films. The structural and morphological properties of the interfacial monolayers and LB films were investigated using surface pressure-area isotherms, Brewster angle microscopy, polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS) and quartz crystal microbalance.
View Article and Find Full Text PDFLangmuir
September 2025
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, Assam 781039, India.
Simultaneous sensing and quantification of pharmaceutically active compounds (PhACs) are crucial for protecting the environment and maintaining long-term ecological sustainability. This study focuses on the bio-based synthesis of BiS-ZnO nanocomposites (BiS-ZnO(bio)) using bio-extract for dual-analyte selective and simultaneous electrochemical monitoring of phenylbutazone (PBZ) and sulfamethoxazole (SMZ) in the environmental matrices. BiS-ZnO(bio) exhibited ZnO(bio) nanostructures embedded on BiS(bio) nanorods with an average rod length of 1409.
View Article and Find Full Text PDFMikrochim Acta
September 2025
Key Laboratory of Water Security and Water Environment Protection in Plateau Intersection (NWNU), Ministry of Education, Northwest Normal University, Lanzhou, 730070, China.
An electrochemical sensor based on MXene/PANI/SnO nanomaterials was developed for the detection of 4-aminophenol (4-AP). In situ oxidative growth of PANI on the MXene surface effectively hindered the stacking of the lamellae and increased the specific surface area of the composites. Further complexation of tin dioxide with swelling properties of the structure provided adsorption and catalytic sites for 4-AP.
View Article and Find Full Text PDFDalton Trans
September 2025
Sun Yat-Sen University, MOE Laboratory of Polymeric Composite and Functional Materials, School of Materials Science and Engineering, Guangzhou 510275, China.
The main bottleneck faced by traditional hydrogen production technology through water electrolysis lies in the high energy consumption of the anodic oxygen evolution reaction (OER). Combining the thermodynamically favorable ethanol oxidation reaction (EOR) with the hydrogen evolution reaction provides a promising route to reduce the energy consumption of hydrogen production and generate high value-added products. In this study, a facile method was developed for nickel oxyhydroxide (NiOOH) fabrication.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave., Madison, Wisconsin 53706, United States.
Slippery liquid-infused porous surfaces (or "SLIPS") can prevent bacterial surface fouling, but they do not inherently possess the means to kill bacteria or reduce cell loads in surrounding media. Past reports show that the infused liquids in these materials can be leveraged to load and release antimicrobial agents, but these approaches are generally limited to the use of hydrophobic agents that are soluble in the infused oily phases. Here, we report the design of so-called "proto-SLIPS" that address this limitation and permit the release of highly water-soluble (or oil-insoluble) agents.
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