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This study investigates the synergistic effects of crystal habit and confining pressure on the compressive mechanical behavior of crystalline rocks using a grain-based model implemented in the Universal Distinct Element Code. Synthetic granite samples with euhedral, subhedral, and anhedral microstructures were simulated by adjusting grain boundary irregularity, quantified by fractal dimension (D), which increased from euhedral to anhedral. Deformation and failure were depicted using a compression-hardening contact model and a cohesion-weakening-friction-strengthening material model. Results show that Young's modulus and Poisson's ratio nonlinearly increased with confining pressure, insensitive to crystal habit. Under low confining pressure, compressive stress-strain curves exhibited significant dispersion during crack damage due to crystal habit variations. However, pre-peak curves increasingly overlapped at higher pressures, while post-peak curves remained dispersed. Peak compressive strength initially decreased and then increased with D under low pressure, but this trend diminished as pressure rose. Strength followed the Hoek-Brown criterion, with envelopes dispersing at low pressure but converging under higher pressure. Hoek-Brown parameters first increased and then decreased with D. Tensile stress magnitude and the number of concentration zones increased with increasing D but were suppressed by higher pressure, reducing their influence. As confining pressure increased, tensile stress concentration effects were inhibited, while grain contact shear strength increased, eventually matching grain material strength, diminishing the role of crystal habit and making confining pressure dominant. Additionally, with increasing D and confining pressure, intergranular cracks decreased in number and length, while intragranular damage zones became denser, highlighting the interplay between microstructure heterogeneity and stress state in controlling failure mechanisms.
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http://dx.doi.org/10.1038/s41598-025-02322-2 | DOI Listing |
Introduction: Pressure injuries (PIs) in patients with diabetes mellitus (DM) still impacts patients' health and places a heavy burden on healthcare systems. Stage I and stage II PIs are particularly prevalent among individuals with diabetes. Without timely and appropriate interventions, these injuries can progress to more severe stages, requiring prolonged recovery periods.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemical Engineering, National Taiwan University, Taipei 106319, Taiwan.
To address the increasingly limited water availability, using metal-organic frameworks (MOFs) to capture atmospheric water vapor as usable resources has emerged as a promising strategy. The adsorption characteristics of MOFs as well as their step pressure (i.e.
View Article and Find Full Text PDFRev Sci Instrum
September 2025
Department of Earth Sciences, University College London, London, United Kingdom.
We have developed a new true triaxial apparatus for rock deformation, featuring six servo-controlled loading rams capable of applying maximum stresses of 220 MPa along the two horizontal axes and 400 MPa along the vertical axis to cubic rock samples of 50 mm side. Samples are introduced into a steel vessel, allowing rock specimens to be subjected to confining pressures of up to 60 MPa. Pore fluid lines connected to two pump intensifiers enable high-precision permeability measurements along all three principal stress directions.
View Article and Find Full Text PDFLangmuir
September 2025
Department of Mechanical and Industrial Engineering, Montana State University, Bozeman, Montana 59717, United States.
Global challenges posed by freshwater scarcity and the water-energy nexus drive demand for novel macromolecular design of tailored nanostructures endowed with a variety of hydrophilic and hydrophobic features. Offering potential to meet this demand, metal-organic framework (MOF) materials are synthesized from coordinated formations that create versatile reticular structures with variable water adsorption affinities. However, advances in the fundamental understanding of water interactions within these structures are impeded by the failure of classical analyses to identify mechanisms of interaction, connect fundamental isotherm types, and provide appropriate benchmarks for assessment.
View Article and Find Full Text PDFPressure ulcer (PU) cause metabolic disorders and ischemia via prolonged pressure, leading to secondary infection, inflammation, and vascular neuropathy. However, existing therapies rely on microenvironment, HO, low repair efficiency, and lack efficient collaborative therapy. Herein, a confined multifunctional TiO/Pt nanozyme is developed via atomic layer deposition for PUs repair.
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