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Due to its widespread distribution in industrial, commercial, and residential settings, xylene detection is crucial. In this study, carbon sphere templates and NaHCO etching were used to synergistically prepare WO with uniform macropores, which was then decorated with Au elements. The findings demonstrated that the Au-decorated WO-etched sample (WO-1%E+Au) had the best sensing performance for 100 ppm xylene (response value: 21.3, optimal operating temperature: 360 °C) and short response/recovery time (1 s/11 s). The etching of NaHCO and the synergistic carbon sphere templates were responsible for the sensing performance, as they enhanced the sample surface's specific surface area and roughness while also supplying additional active sites. Furthermore, the sensor's sensitivity and selectivity to xylene were enhanced by the coupling effect and dehydrogenation catalysis of the noble metal Au. The results of this work advance our knowledge of gas-sensing mechanisms and offer guidance for the creation of extremely sensitive and selective xylene gas sensors.
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http://dx.doi.org/10.3390/mi16060646 | DOI Listing |
J Chromatogr A
September 2025
Environment Research Institute, Shandong University, Qingdao, 266237, China. Electronic address:
On-site accurate and real-time monitoring of trace chemical warfare agents is a critical component of national security surveillance. In this study, a photoionization-induced chemical ionization time-of-flight mass spectrometry is developed for the detection of trace gaseous chemical warfare agents under ambient conditions. Firstly, a benzene-toluene-xylene mixture standard gas is utilized to optimize the instrument parameters, followed by screening of dopants for chemical warfare agents detection, with methanol ultimately identified as the optimal dopant.
View Article and Find Full Text PDFJ Chromatogr A
September 2025
Luoyang R&D Center of Technology, SINOPEC Engineering (Group) Co., Ltd, Luoyang 471003, China. Electronic address:
Conventional one-dimensional gas chromatography methods for gasoline quality monitoring require separate analyses for different component classes, limiting analytical efficiency and unconventional additive detection. This study presents a comprehensive two-dimensional gas chromatography with flame ionization detection (GC × GC-FID) platform enabling simultaneous quantification of regulated components and rapid screening of unconventional additives in a single analytical run. The method achieved excellent agreement with ASTM standards and high repeatability for BTEX (benzene, toluene, ethylbenzene, and xylenes) and oxygenates in gasoline.
View Article and Find Full Text PDFToxics
August 2025
Department of Biology, University of Naples Federico II, 80126 Naples, Italy.
Polystyrene microfragments are among the most common plastic pollutants globally. They significantly affect aquatic life, harming various organs and tissues. In this study, we examined the effects of 3 µm polystyrene beads (MPs, 20 µg/L) on development and yolk resorption in pre-feeding nauplii of , a lecithotrophic crustacean used in toxicity testing.
View Article and Find Full Text PDFACS Sens
August 2025
College of Information Science and Engineering, Northeastern University, Shenyang 110819, China.
The properties of xylene-sensing materials are currently limited by size effects and electronic orbital configurations. This work introduces a synthesis strategy utilizing the unique structural characteristics and physicochemical properties of protein hydrogels to create spatially confined domains. Uniformly dispersed sub-10 nm S-doped InO cubes were successfully prepared, which are the smallest known InO cubes.
View Article and Find Full Text PDFVet Comp Oncol
August 2025
Department of Medical Sciences, University of Wisconsin-Madison, Madison, Wisconsin, USA.
Canine multicentric lymphoma is a common cancer in dogs without evidence-based prevention measures. While breed accounts for part of lymphoma risk, environmental exposures might also contribute. Human non-Hodgkin lymphoma (NHL), which resembles canine lymphoma, is associated with exposures to volatile organic compounds (VOCs) and herbicides.
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