Scalable Synthesis of CsPbX Quantum Dot-Organic Hybrid Microrings for Low Threshold Lasing.

J Phys Chem Lett

Institute of Molecular Plus (IMP), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), National Industry-Education Platform for Energy Storage (Tianjin), Tianjin University, Tianjin 300072, P. R. China.

Published: July 2025


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Article Abstract

Perovskite colloidal quantum dots (PQDs) are nanoscale crystals renowned for their exceptional optical properties, making them ideal for next-generation laser technologies. Their solution-processability supports thin-film fabrication and microcavity integration, yet micro-nano laser development remains challenging. In this study, we present a template-confined growth approach to fabricate hybrid microring (HMR) arrays, embedding PQDs within a 4,4'-bis(9-carbazolyl)-1,1'-biphenyl (CBP) matrix. This method produces uniform structures with improved processability. Structural characterization reveals a vertically graded PQD distribution, with higher concentrations near the substrate due to accumulation during CBP's bottom-up precipitation. CBP integration enhances processability and lowers PQD density, suppressing Auger recombination. These HMRs, featuring smooth surfaces, serve as efficient whispering gallery mode (WGM) resonators, achieving laser emission at a threshold of 6.64 μJ cm and a quality factor of 1808. Tunable ring dimensions enable precise mode control, while scalability supports large-area production of blue, green, and red HMRs, advancing integrated photonics.

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http://dx.doi.org/10.1021/acs.jpclett.5c01111DOI Listing

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