98%
921
2 minutes
20
We develop a method to calculate generic time-dependent correlation functions for inhomogeneous quantum quenches in (1+1)-dimensional conformal field theory (CFT) induced by sudden Hamiltonian deformations that modulate the energy density inhomogeneously. Our Letter particularly focuses on the effects of spatial boundaries, which have remained unresolved by previous analytical methods. For generic postquench Hamiltonian, we develop a generic method to calculate the correlations by mirroring the system, which otherwise are Euclidean path integrals in complicated spacetime geometries difficult to calculate. On the other hand, for a special class of inhomogeneous postquench Hamiltonians, including the Möbius and sine-square-deformation Hamiltonians, we show that the quantum quenches exhibit simple boundary effects calculable from Euclidean path integrals in a straightforward strip spacetime geometry. Applying our method to the time evolution of entanglement entropy, we find that, for generic cases, the entanglement entropy shows discontinuities (shockwave fronts) propagating from the boundaries. In contrast, such discontinuities are absent in cases with simple boundary effects. We verify that our generic CFT formula matches well with numerical calculations from free-fermion tight-binding models for various quench scenarios.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.134.220404 | DOI Listing |
Angew Chem Int Ed Engl
September 2025
Shaanxi Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Department of Chemistry and Chemical Engineering, ShaanXi Normal University, Xi'an, 710062, P.R. China.
Rhodamine derivatives exhibiting inverted open-closed form fluorescence behavior redefines conventional photochemical paradigms while illuminating new structure-property relationships and fascinating application potentials. Herein, we report a donor-acceptor engineering strategy that activates closed form emission in rhodamines, achieving unprecedented Stokes shifts (>280 nm) while overcoming aggregation-caused quenching. The new class of rhodamines with inverted open-close form emission behavior are created through simultaneous substitution of N,N-diethyl groups with indole (donor) and conversion of spiro-lactam to benzene sulfonamide (acceptor).
View Article and Find Full Text PDFAnal Bioanal Chem
September 2025
Hebei Key Laboratory of Public Health Safety, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, College of Public Health, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, China.
This work presents the development of a highly sensitive, selective, and efficient aptamer-based fluorescent sensor for detecting cortisol in human urine. Carbon quantum dots-nucleic acid aptamer (CQDs-Apt) synthesized with excellent photoluminescent properties and stability, were selected as the fluorescent probe. In the presence of MoS-NSs, CQDs-Apt adsorbed onto the surface of MoS-NSs via electrostatic and π-π interactions, leading to strong and rapid fluorescence quenching due to static quenching mechanism between them.
View Article and Find Full Text PDFBiosens Bioelectron
September 2025
College of Chemistry, Jilin Province Research Center for Engineering and Technology of Spectral Analytical Instruments, Jilin University, Qianjin Street 2699, Changchun, 130012, China. Electronic address:
Papillary thyroid carcinoma (PTC) is the most prevalent form of thyroid cancer with a high incidence among endocrine malignancies. It tends to metastasize early in lymph nodes and differs markedly from other subtypes in biological behavior, clinical management, and prognosis. Therefore, accurately distinguishing PTC from other pathological subtypes is crucial for guiding diagnosis and treatment decisions.
View Article and Find Full Text PDFACS Omega
September 2025
Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro (IMA/UFRJ), Rio de Janeiro, Rio de Janeiro 21941-598, Brazil.
This study reports the synthesis and functionalization of poly-(-vinylcarbazole) (PVK) with anthracene units to enhance its blue photoluminescence properties. Structural and thermal analyses confirmed successful incorporation of anthracene moieties into the PVK backbone at an approximate 3:1 ratio of PVK repeat unit to anthracene. Photophysical characterization showed that anthracene-functionalized PVK (PVK-An) retained blue-region emission (432 nm), although with reduced emission efficiency due to π-π stacking interactions.
View Article and Find Full Text PDFACS Omega
September 2025
Tecnologico de Monterrey, Escuela de Ingeniería y Ciencias, Ave. Eugenio Garza Sada 2501, Monterrey 64849, Mexico.
In this work, carbon nanodots (CNDs) were synthesized via a pyrolysis carbonization method using petals. The synthesized CNDs exhibit optical absorption in the UV region, with a tail extending out into the visible range. When these CNDs interact with Ho ions through charge transfer processes, they form an RE-CNDs hybrid (Rare Earth-CNDs hybrid), resulting in fluorescence quenching in an aqueous solution.
View Article and Find Full Text PDF