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Copper slag, a secondary product generated from the copper refining process, which contains an extensive amount of valuable metals and harmful elements such as Fe, Cu, Zn, Co, Ni, Pb, As, etc. The massive accumulation and limited value-added utilization of copper slag have caused serious environmental pollution and resource waste. In order to realize the resourceful and high-value comprehensive utilization of copper slag, the efficient separation and recovery of valued metals from copper slag has garnered significant attention. In this work, a review of the extraction and recycling processes for valued metals from copper slag was presented, and the production process, physicochemical properties, and microstructure of copper slag were introduced. Several typical processes for the separation and recovery of valued metals from copper slag have been thoroughly compared and summarized, including flotation, pyrometallurgical, and hydrometallurgical methods. In addition, the current development status of extracting valuable heavy metals from copper slag was analyzed, and the main challenges it faces were summarized and discussed, aiming to promote the resource utilization and high-value utilization of copper slag.
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http://dx.doi.org/10.1016/j.envres.2025.122145 | DOI Listing |
RSC Adv
August 2025
Yunnan Academy of Ecological and Environmental Sciences Kunming 650034 China.
A process route combining flotation for recovering easily floatable sulfide copper minerals and oxygen pressure acid leaching (OPAL) was employed to comprehensively recover valuable metals (Cu, Mo, Fe, ) from copper smelting slag with a high oxidation degree. The oxidative leaching process selectively dissolved and recovered Cu and Mo while transforming Fe into leach residue, rendering it suitable as a raw material for iron and steel smelting. Under optimal conditions, the leaching recoveries for Cu and Mo reached 96.
View Article and Find Full Text PDFUltrason Sonochem
September 2025
School of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 Yunnan, PR China; National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093 Yunnan, PR China; Faculty of Metallurgy and Mining, K
The cementation method has become the dominant method for recovering cadmium from copper-cadmium slag leach solution due to its low cost and safety features. However, the conventional method has several limitations, including low zinc powder utilization, low sponge cadmium purity, and an extended production cycle. These limitations primarily stem from zinc powder agglomeration and the subsequent coverage of zinc particles by the product layer.
View Article and Find Full Text PDFSci Rep
August 2025
Department of Civil Engineering, College of Engineering and Technology, Mattu University, Metu, 318, Ethiopia.
This study investigates the thermal and mechanical performance of geopolymer concrete incorporating recycled coarse aggregate (RCA) and copper slag (CS) as sustainable alternatives to natural aggregates. The geopolymer binder comprises fly ash (FA) and ground granulated blast furnace slag (GGBS), activated by a 12 M NaOH solution. RCA replaced 30% of natural coarse aggregate to form recycled aggregate concrete (RAC), while CS replaced natural fine aggregate in 20% increments up to 100% in RCA based geopolymer concrete to study its effect on compressive, split-tensile, and flexural strengths at ambient (27 °C) and elevated temperatures (100 °C, 300 °C, 500 °C, 700 °C).
View Article and Find Full Text PDFPLoS One
August 2025
Zinman Institute of Archaeology, University of Haifa, Haifa, Israel.
Sci Rep
August 2025
Łukasiewicz Research Network- Institute of Non-Ferrous Metals, ul. Sowińskiego 5, Gliwice, 44-100, Poland.
Shaft sludge is a lead-bearing material produced by the wet dedusting of shaft furnace process gases generated during copper smelting from concentrates. It is a material with a high concentration of lead and hydrocarbon compounds, the melting of which in short rotary furnaces causes many problems. This paper presents the results of thermodynamic modelling of the melting process of shaft sludge and other lead-bearing materials.
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