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Traditional landfill cover materials have low strength and poor dry-wet durability. Municipal solid waste incineration fly ash (MSWI FA) can be used to partially replace cement solidification dredging sediment (DS). This article investigates the possibility of using MSWI FA and ordinary Portland cement (OPC) composite cured DS as a covering material. The mechanical properties, permeability, and wet-dry durability of the cured system were investigated under the conditions of MSWI FA content ranging from 0% to 60% and OPC content ranging from 10% to 15%. The microscopic mechanism was analyzed by scanning electron microscopy and X-ray diffraction. The results showed that when the OPC and MSWI FA contents were 15% and 20%, respectively, the comprehensive performance of the cured specimens was best after 28 days of natural curing. The unconfined compressive strength reached 1993.9 kPa, and the permeability coefficient decreased to below 1 × 10 cm/s, fully meeting the requirements for landfill coverage. C-S-H gel is the main strength source of the solidified body, while Friedel salt and ettringite enhance the compactness of the matrix. An excessive moisture environment promotes the water absorption of soluble salts produced by MSWI FA hydration, leading to sample expansion and reduced strength. MSWI FA and OPC cured DS exhibit good compression performance in the intermediate cover system of landfills, and can maintain good engineering performance under periodic dry-wet cycles. This dual strategic synergy solves the hazardous disposal problem of MSWI FA and the resource utilization demand of DS, demonstrating enormous application potential.
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http://dx.doi.org/10.3390/ma18112622 | DOI Listing |
Arch Environ Contam Toxicol
September 2025
Ecole Polytechnique Fédérale de Lausanne (EPFL), School of Architecture, Civil and Environmental Engineering, 1015, Lausanne, Switzerland.
Pollution from past industrial activities can remain unnoticed for years or even decades because the pollutant has only recently gained attention or been identified by measurements. Modeling the emission history of pollution is essential for estimating population exposure and apportioning potential liability among stakeholders. This paper proposes a novel approach for reconstructing the history of polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) pollution from municipal solid waste incinerators (MSWIs) with unknown past emissions.
View Article and Find Full Text PDFJ Environ Manage
September 2025
Interdisciplinary Research Center for Construction and Building Materials, Department of Materials Science and Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia.
The disposal of municipal solid waste incineration fly ashes (MSWI-FA) is complicated by soluble chlorides, which increase the risk of heavy metals (HMs) leaching toxicity and hinder the further use of remediated MSWI-FA. In this study, the self-assembly potentiality of magnesium oxychloride cement (MOC) in geopolymerization was explored and utilized to enhance the solidification/stabilization (S/S) of the MSWI-FA. The MOC-self-assembled geopolymerization kinetics can be suitably described by the JMAK model.
View Article and Find Full Text PDFEnviron Sci Technol
August 2025
CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China.
The catalytic mechanisms underlying the formation of polybrominated dibenzo--dioxins and dibenzofurans (PBDD/Fs) have emerged as a critical environmental concern, particularly regarding the roles of metal- and metalloid-based catalysts. Although these catalysts are recognized as crucial agents for the formation of PBDD/Fs, there is still significant knowledge gaps in identifying the active species and quantifying their catalytic activities. This study systematically investigates four key reaction pathways governing PBDD/Fs formation: aromatic bromination, the Deacon reaction, the precursor, and the de novo synthesis process.
View Article and Find Full Text PDFToxics
August 2025
School of Engineering, Hangzhou Normal University, Hangzhou 310018, China.
Municipal solid waste incineration fly ash (MSWI FA) is recognized as a hazardous solid waste due to its enrichment in toxic heavy metals and high leaching potential. This review systematically summarizes the current understanding of heavy metal occurrence in MSWI FA and associated environmental risks. Solidification and stabilization methods, such as cement-based curing and chemical immobilization, are widely applied due to their cost-effectiveness and operability, though their long-term stability and recovery potential remain limited.
View Article and Find Full Text PDFJ Environ Manage
August 2025
University of Bologna, Department of Biological, Geological and Environmental Sciences (BiGeA), Piazza di Porta San Donato, 1, Bologna, Italy; National Research Council of Italy (CNR), Department of Scienze Del Sistema Terra e Tecnologie per l'Ambiente, Marine science institute (ISMAR), Napoli Resea
Municipal Solid Waste Incineration (MSWI) plants pose significant environmental concerns, generating solid by-products, namely Fly Ash (FA) and Bottom Ash (BA). These MSWI residues have received attention due to the presence of valuable elements, Potentially Toxic Elements (PTE), and other contaminants. Radionuclide detection is also critical because they can concentrate in incineration ashes to pose a radiological hazard.
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