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Coconut water is a nutritious beverage that is susceptible to deterioration. This study aimed to elucidate the deterioration mechanism of coconut water by integrating aquaphotomics, metabolomics, and 16S rDNA analysis. Aquaphotomics revealed primary association of quality deterioration with hydrogen bond vibrations and O-H vibrations at room temperature and cold storage, respectively. Metabolomics identified gamma-linolenic acid and xanthosine as the most significant differential metabolites at room temperature and cold storage, respectively. 16S rDNA analysis revealed that the dominant biomarkers during the deterioration process at room temperature were Enterobacter and Kluyvera, whereas under cold storage, the quality degradation was associated with Serratia and Pseudomonas. Correlation analysis revealed the oxidation of gamma-linolenic acid and L-methionine S-oxide by Enterobacter and Citrobacter, resulting in increased 12,13-DHOME level and deterioration at room temperature. During cold storage, Pseudomonas decomposed proteins and fats, which were subsequently converted into acids and gases by Serratia, thereby contributing to deterioration.
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http://dx.doi.org/10.1016/j.foodchem.2025.145042 | DOI Listing |
ACS Nano
September 2025
Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States.
Integration of ultrathin, high-quality gate insulators is critical to the success of two-dimensional (2D) semiconductor transistors in next-generation nanoelectronics. Here, we investigate the impact of atomic layer deposition (ALD) precursor choice on the nucleation and growth of insulators on monolayer MoS. Surveying a series of aluminum (AlO) precursors, we observe that increasing the length of the ligands reduces the nucleation delay of alumina on monolayer MoS, a phenomenon that we attribute to improved van der Waals dispersion interactions with the 2D material.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute Jatni, Khurda, Bhubaneswar 752050, Odisha, India.
Quantum-confined perovskites represent an emerging class of materials with great potential for optoelectronic applications. Specifically, zero-dimensional (0D) perovskites have garnered significant attention for their unique excitonic properties. However, achieving phase-pure, size-tunable 0D perovskite materials and gaining a clear understanding of their photophysical behavior remains challenging.
View Article and Find Full Text PDFJ Org Chem
September 2025
Organic and Medicinal Chemistry Division, CSIR-Indian Institute of Chemical Biology, 4, Raja S. C. Mullick Road, Jadavpur, Kolkata 700 032, India.
The denitrogenation of tetrazoles is typically performed using transition-metal catalysts at high temperatures due to the inherent stability of the tetrazole group. In this work, we present, for the first time, an electrochemical method for denitrogenating tetrazoles at room temperature. This method employs a sacrificial zinc anode and a platinum cathode in a solvent mixture of acetonitrile and water under a constant current in an undivided cell.
View Article and Find Full Text PDFAdv Physiol Educ
September 2025
Swansea University Medical School, Swansea University, Swansea, UK.
The chick embryo ventricular cardiomyocyte model provides students easy access to experiments involving fundamental features of cardiac cell physiology and pharmacology. Using standard physiology teaching laboratories and basic cell culture equipment, spontaneously beating colonies of electrically-connected cardiomyocytes can be obtained by the students themselves. Students learn, aseptic techniques and cell culture alongside experiments illustrating, at the simplest level of experimentation, how beating rate can be altered physiologically or pharmacologically.
View Article and Find Full Text PDFMacromol Biosci
September 2025
Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, Republic of Korea.
Conventional gelatin's gel-to-sol transition upon heating restricts its utility in biomedical applications that benefit from a gel state at physiological temperatures such as Pluronic F127 and poly(NIPAAm). Herein, we present "rev-Gelatin", a gelatin engineered with reverse thermo-responsive properties that undergoes a sol-to-gel transition as temperature rises from ambient to body temperature. Inspired by the phase dynamics of common materials like candy and ice cubes, whose surfaces soften or partially melt under warming, facilitating inter-object adhesion- rev-Gelatin leverages this concept to achieve fluidity at room temperature for easy injectability.
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