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Article Abstract
A non-classical Ru-based polyoxometalate, NaH[{Ru(bpy)Cl}O(PWO)]·10HO (1), was successfully constructed from mono-vacant heteropolytungstates [PWO] and [Ru(bpy)Cl]. Compound 1 has strong light trapping ability, and the yield of aniline reduced from nitrobenzene under visible light ( > 400 nm) can reach 99.8%. In addition, a range of extended experiments have demonstrated that compound 1 is an effective and stable heterogeneous catalyst in the reaction of nitrobenzene reduction.
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