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Energy materials are essential for addressing global energy challenges, and their design, recycling, and performance optimization are critical for sustainable development. To efficiently rise to this occasion, advanced technology should be explored to address these challenges. This review focuses on the potential of ultrafast thermal engineering as an innovative approach to the design and recycling of energy materials and systematically examines ultrahigh temperature shock's origins, mechanisms, and developmental progress, clarifying fundamental differences between the Joule heating and carbothermal shock modes. Recent advancements in lithium/sodium battery electrode fabrication, catalyst synthesis, and battery recycling by this technology are comprehensively summarized to highlight the processing parameters, structural modulation mechanisms, and underlying principles. The review also explores the mechanisms of ultrahigh temperature shock processes, their scalability, and their environmental and economic implications. Notably, a mechanistic insight into the dynamic coexistence of Joule heating and carbothermal shock in UTS is proposed, which may synergistically govern structural evolution in poor conductivity/insulating materials. This review ultimately aims to drive the development and application of ultrafast thermal engineering in the energy materials field.
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http://dx.doi.org/10.1021/acsnano.5c04768 | DOI Listing |
ACS Nano
September 2025
Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States.
Integration of ultrathin, high-quality gate insulators is critical to the success of two-dimensional (2D) semiconductor transistors in next-generation nanoelectronics. Here, we investigate the impact of atomic layer deposition (ALD) precursor choice on the nucleation and growth of insulators on monolayer MoS. Surveying a series of aluminum (AlO) precursors, we observe that increasing the length of the ligands reduces the nucleation delay of alumina on monolayer MoS, a phenomenon that we attribute to improved van der Waals dispersion interactions with the 2D material.
View Article and Find Full Text PDFInorg Chem
September 2025
Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076, India.
A potential replacement that alleviates the shortcomings of the dominant light absorber materials used in solar photovoltaics has been synthesized, and its microstructural, electronic structure, and optical properties have been investigated. KCuS crystals were synthesized by the carbonate method. Transmission electron microscopy (TEM) established [010] as the growth direction of the needle-like monoclinic crystals.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
College of Chemistry and Chemical Engineering, Instrumental Analysis Center of Qingdao University, Qingdao Application Technology Innovation Center of Photoelectric Biosensing for Clinical Diagnosis and Treatment, Shandong Sino-Japanese Center for Collaborative Research of Carbon Nanomaterials, Qing
Silk fibroin (SF)-based flexible electronic/photonic materials have gained great attention in wearable devices and soft sensors. However, it remains challenging to understand the molecular interaction mechanisms and subsequently fabricate SF-based flexible materials that exhibit fluorescence, humidity sensitivity, and conductivity properties. In this study, by incorporating lanthanide europium ion (Eu), the design and fabrication of a flexible, fluorescent, and conductive SF membrane was proposed.
View Article and Find Full Text PDFJ Occup Environ Hyg
September 2025
Division of Biology, Chemistry, and Materials Science, Office of Science and Engineering Laboratories, US Food and Drug Administration (FDA), Oak Ridge, Tennessee.
This work assesses the current characterization framework of single-use personal protective equipment (PPE) per recognized consensus standards and presents a novel quantitative approach to refining characterization of barrier materials and predicting PPE performance. Scanning electron microscopy (SEM) and image analysis software (Diameter J) were used to examine the microscopic fiber and pore structure of filter layers of surgical N95 filtering facepiece respirators, before and after exposure to chemicals used in decontamination modalities (vaporized hydrogen peroxide or ozone). The effect of porosity on penetration was assessed by bacterial filtration efficiency (BFE) testing.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central Minzu University, Wuhan 430074, China.
In contrast to metal ions that have been routinely used to construct metal-organic frameworks (MOFs), anions have rarely been used as essential coordination centers in supramolecular organic frameworks (SOFs). In this work, we present a SOF, , based on the coordination of chloride anions and a flexible oligopyrrole. Owing to the multiple interactions between individual oligopyrrole molecules and an A-B-C-style stacking of the 2D honeycomb layers, crystalline exhibits reasonable thermal stability and retains its structure upon desolvation.
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