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Article Abstract
We report the synthesis and characterization of heteroatom-incorporated norbornadiene (NBD) derivatives. Push-pull substitution on the 2 and 3 position as well as introduction of oxygen or nitrogen at position 7 of the NBD scaffold have led to the development of a new family of photoswitches. We studied the potential conversion of norbornadiene to quadricyclane (QC) isomers. As main investigation tools, UV-vis and NMR spectroscopy were utilized. We determined significant spectral features of the formed NBD species, including λ and λ values, all of which exhibit redshifts compared to their isocyclic counterparts. Additionally, the selected QC isomers were subjected to thermal and catalytic back-conversion studies.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12035880 | PMC |
| http://dx.doi.org/10.3762/bjoc.21.64 | DOI Listing |
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