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Atomic layer deposition-grown beryllium oxide (BeO) is gaining attention as a dielectric material that can minimize device power consumption because of its high dielectric constant, high thermal conductivity, and low leakage current enabled by its wide bandgap energy. In this study, the impact of BeO dielectrics on InSnZnO (ITZO) thin-film transistors (TFTs) was investigated, revealing that adding a hafnium dioxide (HfO) layer can enhance electrical performance and bias stress reliability. Time-of-flight secondary-ion mass spectrometry and X-ray photoelectron spectroscopy confirmed that the single-BeO dielectric-based ITZO TFTs exhibited a low mobility of 27.6 cm/V·s due to Be migration and demonstrated abnormal threshold voltage () shifts under bias stress. Conversely, the HfO 20 nm/BeO hetero-dielectric ITZO TFTs exhibited a high mobility of 76.6 cm/V·s and enhanced abnormal shift characteristics. Therefore, these results demonstrate that our high-performance HfO/BeO hetero-dielectric-based ITZO TFTs could be utilized in back-end-of-line devices for monolithic three-dimensional memory technologies.
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http://dx.doi.org/10.1021/acs.nanolett.5c00552 | DOI Listing |
Nanotechnology
June 2025
Fudan University, Handan Road 220, Yangpu Disctrict, Shanghai, Shanghai, Shanghai, 200433, CHINA.
DRAM technology is crucial in modern integrated circuits. However, the conventional 1T1C DRAM is approaching its limitations in scalability near 10 nm technical node, posing challenges for storage capacity and integration. Therefore, research has focused on incorporating 3D-stacking DRAM to enhance both capacity and integration.
View Article and Find Full Text PDFNano Lett
April 2025
School of Integrated Technology, Yonsei University, Seoul 03722, Republic of Korea.
Atomic layer deposition-grown beryllium oxide (BeO) is gaining attention as a dielectric material that can minimize device power consumption because of its high dielectric constant, high thermal conductivity, and low leakage current enabled by its wide bandgap energy. In this study, the impact of BeO dielectrics on InSnZnO (ITZO) thin-film transistors (TFTs) was investigated, revealing that adding a hafnium dioxide (HfO) layer can enhance electrical performance and bias stress reliability. Time-of-flight secondary-ion mass spectrometry and X-ray photoelectron spectroscopy confirmed that the single-BeO dielectric-based ITZO TFTs exhibited a low mobility of 27.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2025
Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, State Key Laboratory of Luminescent Materials and Devices, School of Materials Sciences and Engineering, South China University of Technology, Guangzhou 510640, China.
Atomic layer deposition (ALD) is advantageous in the flexible and precise control of the composition and thickness of thin films. However, the nucleation delay during the deposition of multicomponent films leads to unexpected thickness and composition, the mechanism of which is still ambiguous. Herein, we reveal that the surface formed by a certain precursor is self-limiting for itself; there remain interstitial sites for other precursors.
View Article and Find Full Text PDFACS Omega
March 2025
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Wushan Road 381, Guangzhou 510640, China.
The trade-off between mobility and stability is the main problem for amorphous oxide semiconductor (AOS) thin-film transistors (TFTs). In this work, a high-mobility and good-photostability Tb-doped indium-tin-zinc oxide (Tb:ITZO) AOS is studied. The ITZO TFT without Tb doping had a mobility of as high as 49.
View Article and Find Full Text PDFJ Chem Phys
February 2025
School of Microelectronics, Fudan University, Shanghai 200433, China.