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The synthesis of uniform, low-defect graphene on copper foil is approaching an industrial scale. However, its practical application remains challenging due to the lack of an appropriate method for its clean transfer to a device substrate. In this study, we demonstrate the use of a lift-off resist (LOR) photoresist as a transfer-supporting layer, resulting in a truly clean transfer of graphene. The surface cleanliness of graphene was assessed through optical microscopy, atomic force microscopy, and Raman spectroscopy. The uniform sensing characteristics of the cleanly transferred graphene were further evidenced by the first-ever implementation of high-throughput graphene field-effect transistors, distinct from those covered with a thin layer of amorphous carbon, such as residual poly(methyl methacrylate). This transfer method provides a novel alternative route for graphene transfer.
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http://dx.doi.org/10.1021/acssensors.4c02816 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China.
The development of anode materials for lithium-ion batteries must meet the demands for high safety, high energy density, and fast-charging performance. TiNbO is notable for its high theoretical specific capacity, low structural strain, and exceptional fast-charging capability, attributed to its Wadsley-Roth crystal structure. However, its inherently poor conductivity has hindered its practical application.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
Università di Roma La Sapienza, Dipartimento di Fisica, Piazzale Aldo Moro 5, I-00185 Roma, Italy.
We develop an ab initio framework that captures the impact of electron-electron and electron-hole interactions on phonon properties. This enables the inclusion of excitonic effects in the optical phonon dispersions and lifetimes of graphene, both near the center (Γ) and at the border (K) of the Brillouin zone, at phonon-momenta relevant for Raman scattering and for the onset of the intrinsic electrical resistivity. Near K, we find a phonon redshift of ∼150 cm^{-1} and a 10× enhancement of the group velocity, together with a 5× increase in linewidths due to a 26× increase of the electron-phonon matrix elements.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States.
Carbon dots (CDs) represent a new class of nontoxic and sustainable nanomaterials with increasing applications. Among them, bright and large Stokes-shift CDs are highly desirable for display and imaging, yet the emission mechanisms remain unclear. We obtained structural signatures for the recently engineered green and red CDs by ground-state femtosecond stimulated Raman spectroscopy (FSRS), then synthesized orange CDs with similar size but much higher nitrogen dopants than red CDs.
View Article and Find Full Text PDFNanoscale
September 2025
Fujian Key Laboratory of Drug Target Discovery and Structural and Functional Research, Higher Educational Key Laboratory for Nano Biomedical Technology of Fujian Province, The School of Pharmacy, Fujian Medical University, Fuzhou, Fujian 350122, People's Republic of China.
The rational design of non-precious metal catalysts as a replacement for Pd is of great importance for catalyzing various important chemical reactions. To realize this purpose, the palladium-like superatom NbN was doped into a defective graphene quantum dot (GQD) model with a double-vacancy site to design a novel single superatom catalyst, namely, NbN@GQD, based on density functional theory (DFT), and its catalytic activity for the Suzuki reaction was theoretically investigated. Our results reveal that this designed catalyst exhibits satisfactory activity with a small rate-limiting energy barrier of 25.
View Article and Find Full Text PDFACS Nano
September 2025
CINBIO and Departamento de Química Orgánica. Campus Lagoas-Marcosende, Universidade de Vigo, Vigo E-36310, Spain.
Archimedean spirals are architectural motifs that are found in nature. The facial asymmetry of amphiphilic molecules or macromolecules has been a key parameter in the preparation of these well-organized two-dimensional nanostructures in the laboratory. This facial asymmetry is also present in the helical grooves of chiral helical substituted poly(phenylacetylene)s (PPAs) and poly(diphenylacetylene)s (PDPAs), making them excellent candidates for self-assembly into 2D Archimedean nanospirals or nanotoroids.
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