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Exceptional points (EPs), known as non-Hermitian degeneracies featuring missing eigenspace dimensions, have led to a variety of intriguing wave phenomena in various physical platforms. Chiral EPs collapsing in two orthogonal eigenstates can lead to unique effects and applications, such as loss-induced transparency, EP-enhanced sensing, and chirality-reversal electronics, etc. However, in previous experiments, chiral EPs were typically induced in fixed structures with inherent active gains or nearby nanotips, which are unfavorable for on-chip integrations with low-power elements. Here, we demonstrate the active control of EPs chirality in situ with exceptional-line metasurface. Selective chirality inversion can be well achieved by only light-induced loss without altering the metasurface size. We also perform an ultrafast chirality switch in the picosecond level within transient disturbance. In a broader view, our results provide a platform for the investigation of metasurface-based non-Hermitian physics and active EP modulation, which can stimulate exciting works along this line in near future.
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http://dx.doi.org/10.1103/PhysRevLett.134.106901 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China.
Circularly polarized luminescence (CPL) has emerged as a critical technology for anticounterfeiting and optical display applications due to its unique chiroptical properties. We report a multicolor CPL-emitting elastomeric film (P37/PSK@SiO-PDMS) that synergistically combines chiral helical polyacetylene (P37) and a surface-engineered perovskite (PSK@SiO) through hydrogen-bond-directed assembly. Confinement within the PDMS matrix drives P37 to self-assemble into a chiral supramolecular structure through hydrogen bonding, inducing a chiroptical inversion.
View Article and Find Full Text PDFChemistry
September 2025
Department of Chemistry, School of Science, Institute of Science Tokyo, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8551, Japan.
Expanded helicenes are interesting compounds created by modifying the original helicene structure through the incorporation of linearly fused benzene rings, enlarging the helical diameter. Motivated by Tilley et al.'s report of a key expanded helicene structure in 2017, several research groups have synthesized such nonplanar aromatic compounds, aiming to explore their impressive structures, properties, and chiroptical performance.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2025
State Key Laboratory of Green Pesticide; Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Center for R&D of Fine Chemicals of Guizhou University, Huaxi District, Guiyang, 550025, China.
In contrast to the notable advancements focusing on the preparation of optically enriched S(IV) frameworks in recent years, achieving catalyst stereocontrol over S(VI) stereogenicity to generate chiral S(VI) scaffolds remains a largely underexplored challenge. Herein, we document a new activation mode of isothiourea organocatalysis for the highly enantioselective synthesis of S(VI)-chiral sulfonimidates. This method involves the covalent activation of racemic S(VI) sulfonimidoyl chlorides through the formation of a pivotal isothiourea-bound sulfonimidoyl intermediate.
View Article and Find Full Text PDFThe precise modulation of circular dichroism (CD) is essential for applications in polarization control, sensing, and imaging. Here, we report a novel, to the best of our knowledge, dual-CD response mechanism based on bound states in the continuum (BICs) in an all-dielectric silicon metasurface. By leveraging two distinct topologically protected BICs and converting them into circularly polarized eigenstates, we first demonstrate a reversal of maximum chirality at oblique incidence without requiring any structural alteration.
View Article and Find Full Text PDFAdv Mater
August 2025
Department of Physics, Graduate School, Daegu University, Gyeongbuk, 38453, Republic of Korea.
Weyl metals, known for their topological structure and chiral anomaly, exhibit nonlinear transport that defies conventional theory. In this study, ZrTe, an inversion-symmetric Dirac semimetal tunable to a Weyl state by magnetic field, is investigated, and rectification (alternating current (AC) to direct current (DC) conversion) and third harmonic generation in longitudinal configurations is revealed. Despite its bulk inversion symmetry, symmetry-forbidden rectification and a dynamic phase transition arising from the chiral anomaly are observed.
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