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Achieving adhesion under unfavorable conditions, such as when van der Waals interaction is not available or in dust environments, is crucial in applications ranging from surgical sutures to wound-healing tapes, underwater adhesives, robotic grippers, and space grasping. Interestingly, plants, animals, and microorganisms living in such environmental conditions show surface morphological traits optimized to achieve mechanical interlocking. Thus, they achieve an effective work of adhesion thanks to the interplay of friction and interfacially-storable elastic energy, which otherwise typically suppress adhesion. In this work, the design and fabrication fundamentals for achieving tunable, switchable, and robust mechanical adhesion is provided under a general environmental condition, such as wet or dusty, bio-mimicking natural solutions. A theoretical framework for the design of mechanical adhesion, based on mean-field continuum contact mechanics, is suggested and validated experimentally. This study can pave the way for the development of new technologies to be employed in situations where conventional adhesives may be ineffective, such as for surfaces exposed to water, solvent vapors, lubricants, high temperatures, dusty environments, high vacuum, or aerospace applications, or processes where switching and selective adhesion is needed such as grasping and sorting applications in the semiconductor industry.
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http://dx.doi.org/10.1002/smll.202410527 | DOI Listing |
Nat Commun
September 2025
Physikalisches Institut, Karlsruhe Institute of Technology, Karlsruhe, Germany.
Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and scalability for larger structures. An essential component, in addition to the qubits themselves, is switchable qubit-qubit interactions that can be individually addressed.
View Article and Find Full Text PDFPhotochem Photobiol Sci
September 2025
Faculity of Engineering, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa, 240-8501, Japan.
In recent years, fluorescence-switchable molecules have garnered significant attention as fluorescent dyes for super-resolution fluorescence microscopy, which is increasingly demanded in the field of biochemical imaging. Among such molecules, diarylethene-S,S,S',S'-tetraoxide derivatives have proven particularly promising due to their ability to achieve high contrast fluorescence switching. Diarylethenes incorporating perfluorocyclopentene as the ethene bridge have become the standard scaffold due to their excellent fatigue resistance and thermal stability.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Wenzhou Institute, University of Chinese Academy of Sciences, Wenzhou 325001, China; Terahertz Technology Innovation Research Institute, Terahertz Spectrum and Imaging Technology Cooperative Innovation Center, Shanghai Key Lab of Modern Optical System, School of Optical-Electrical and Computer Engin
Precise engineering of hydrophobic microenvironments in synthetic peptide-catecholamine co-assemblies remains challenging for tunable fluorescence. Hierarchical nanostructures were constructed through sequence-specific peptide encoding (GYK tripeptide and Ac-IIIGYK-NH₂ hexapeptide) and co-assembly with catecholamines of graded hydrophobicity. Structural dynamics were analyzed via molecular simulations, HPLC, AFM, and spectroscopy.
View Article and Find Full Text PDFAnal Methods
September 2025
Shenzhen Key Laboratory for Nano-Biosensing Technology, School of Biomedical Engineering, Shenzhen University Medical School, Shenzhen University, Shenzhen 518060, China.
Self-assembly is regarded as a facile method to fabricate luminescent nanomaterials with aggregation induced emission (AIE) properties for optical sensor design. In this work, a pH-controlled self-ratiometric sensing platform utilizing aggregation-induced emission (AIE)-active Au(I)-TCEP-Cd(II) nanoaggregates was developed for highly reliable D-penicillamine (DPA) detection. Through stoichiometric coordination with Cd, oligomeric Au(I)-tris(2-carboxyethyl)phosphine (TCEP) complexes could self-assemble into snowflake-like nanoaggregates (∼100 nm) with strong yellow emission (540 nm) and excellent aqueous stability.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
College of Materials Science and Engineering, Hohai University, Nanjing 210098, China.
The integration of terahertz (THz) technology with metasurfaces has attracted attention as it enables the fabrication of compact, high-performance, and tunable photonic devices. However, extensive investigation of metasurfaces was limited to a narrow THz range or manipulating a single mode of electromagnetic waves, absorption, reflection, or transmission, without achieving multi-band or broadband switching. This capability constrains metasurface adaptability in modern and reconfigurable systems.
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