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Entropy production is a key descriptor of out-of-equilibrium behavior in active matter systems, providing insights into both single-particle dynamics and emergent collective phenomena. It helps determine transport coefficients and phoretic velocities and serves as a crucial tool for understanding collective phenomena such as structural transitions, regime shifts, clustering, and self-organization. This study investigates the role of entropy production for individual active (catalytic Janus) particles and in systems of active particles interacting with one another and their environment. We employ a multiscale framework to bridge microscopic particle dynamics and macroscopic behavior, offering a thermodynamic perspective on active matter. These findings enhance our understanding of the fundamental principles governing active particle systems and create new opportunities for addressing unresolved questions in non-equilibrium thermodynamics.
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http://dx.doi.org/10.3390/e27020112 | DOI Listing |
Nanoscale
September 2025
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China.
Although improving the charging cutoff voltage is an effective strategy to increase its capacity, LiCoO ("LCO") undergoes rapid capacity decay due to severe structural and interface degradations at high voltages. Herein, we proposed a multifunctional surface modification by coating nano-sized entropy materials (Li-La-Ti-Zr-Co-O, Nano-MEO). Nano-MEO rivets were constructed on the surface of LCO, which stabilized the fragile surface.
View Article and Find Full Text PDFRSC Adv
September 2025
Otto-von-Guericke-University Magdeburg, Chemical Institute, Chair for Industrial Chemistry Universitätsplatz 2 39106 Magdeburg Germany
This work elucidates the thermo-kinetics of the thermal conversion of cameroonian kaolin to metakaolin as the main product. The thermokinetical parameters (activation energy and pre-exponential factor ) for the kaolin conversion were calculated using model-free methods, the Kissinger-Akahira-Sunrose (KAS) and the Flynn-Wall-Ozawa (FWO) method, and differential methods (Kissinger and Ozawa) additionally including iterative procedures for KAS and FWO methods (KAS-Ir; FWO-Ir). The cameroonian kaolin was heat-treated using three different heating rates, 5, 20 and 40 K min, leading to metakaolin samples named MK-(5), MK-(20) and MK-(40).
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
Guangdong Provincial Key Laboratory of New Energy Materials Service Safety, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518055, China.
Thermocells (TECs) represent a promising technology for sustainable low-grade waste heat (<100 °C) harvesting, offering distinct advantages such as scalability, structural versatility, and high thermopower. However, their practical applications are still hindered by low energy conversion efficiency and stability issues. In recent studies, electrolyte engineering has been highlighted as a critical strategy to enhance their thermopower by regulating the solvation structure and redox ion concentration gradient, thereby improving conversion efficiency.
View Article and Find Full Text PDFJ Mass Spectrom
October 2025
Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Canada.
The strong C-F bond found in per- and poly-fluorinated alkyl substances (PFAS) makes them resistant to degradation and thus persistent in the environment. One of the most common methods for quantifying PFAS in environmental matrices is to use tandem mass spectrometry. However, the dissociation of ions made by deprotonating PFAS alcohols and acids has only been qualitatively explored.
View Article and Find Full Text PDFUltramicroscopy
August 2025
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304W. Green Street, Urbana 61801, IL, USA; Materials Research Laboratory, University of Illinois at Urbana-Champaign, 104 South Goodwin Avenue, Urbana 61801, IL, USA. Electronic address:
Complex face-centered-cubic (FCC) alloys frequently display chemical short-range ordering (CSRO), which can be detected through the analysis of diffuse scattering. However, the interpretation of diffuse scattering is complicated by the presence of defects and thermal diffuse scattering, making it extremely challenging to distinguish CSRO using conventional scattering techniques. This complexity has sparked intense debates regarding the origin of specific diffuse-scattering signals, such as those observed at 1/3{422} and 1/2{311} positions.
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