A comprehensive reconnaissance and risk assessment of rubber additives and their transformation products (RATPs) in groundwater: 1,3-Diphenylguanidine (DPG) as a pressing ecological concern.

The widespread detection of rubber additives and their transformation products (RATPs) in surface water environments is well-documented, but their pollution characteristics in groundwater remain unclear. This study comprehensively revealed the occurrence and distribution of 27 RATPs in groundwater across southern China (n = 212). RATPs were detected in groundwater at total levels of 1.21-2,345 ng/L. The primary compounds detected were 1,3-Diphenylguanidine (DPG), 1,3-diphenylurea (DPU), and 2-hydroxybenzothiazole (2-OH-BTH), each with a detection frequency of 99.5 % and mean concentrations of 125, 58.4, and 51.2 ng/L, respectively. The spatial distribution of RATPs in groundwater shows significant lateral variations but lacks vertical differences. Correlation analysis indicates a strong relationship between the RATPs pollution levels and both the type of groundwater and the level of urban economic development, with karst water exhibiting particularly high pollution levels. Five RATPs exhibited medium to high ecological risks in groundwater. The daily intake of RATPs via groundwater in South China is 3.61 × 10-7.00 × 10 mg/(kg·d). According to the multicriteria evaluation approach and persistence, mobility, and toxicity (PMT) assessment, six RATPs, including DPG, have been identified as high-priority pollutants that require significant attention in groundwater management. This study highlights the contamination characteristics and ecological risks associated with RATPs in groundwater, emphasizing the need for increased focus on these widely used yet inadequately evaluated chemicals in future research.